Abstract
For a long time the majority view has been that phonons are irrelevant to the mechanism of high-temperature superconductivity. However, recent experimental results, including the neutron inelastic scattering measurements reviewed here, seriously challenge this view. We point out that the electron–phonon coupling in the cuprates can be substantially different from that in simple metals because of the covalency and strong electron correlation. In particular certain phonon branches induce substantial intersite charge transfer that can result in a negative electronic dielectric susceptibility. Such a strong electron–phonon coupling of certain modes could form the basis for the phonon mechanism of superconductivity in the cuprates.
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Egami, T. Phonon Mechanism of High-T c Superconductivity. Journal of Superconductivity 15, 373–378 (2002). https://doi.org/10.1023/A:1021026331403
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DOI: https://doi.org/10.1023/A:1021026331403