Study on the Mechanism of CO Formation in Reverse Water Gas Shift Reaction Over Cu/SiO₂ Catalyst by Pulse Reaction, TPD and TPR

Abstract

The mechanism of reverse water gas shift reaction over Cu catalyst was studied by pulse reaction with QMS monitoring, temperature programmed desorption (TPD) and temperature programmed reduction (TPR) of Cu/SiO₂ catalyst. The reduced and/or oxidized copper offered low catalytic activity for the dissociation of CO₂ to CO in the pulse reaction study with 1 ml volume of He/CO₂, but the rate of CO formation was significantly enhanced with H₂ participating in the reaction. The TPD spectra of CO₂ obtained by feeding H₂/CO₂ over copper at 773 K provided strong evidence of the formation of formate at high temperature. The formate derived from the association of H₂ and CO₂ is proposed to be the key intermediate for CO production. The formate dissociation mechanism is the major reaction route for CO production.