Abstract
The electrical conductivity of Н2 – x (NH4) x V9Mo3O32.5 – δ · nH2O xerogel films containing different amounts of ammonium ions and water was measured as a function of temperature. The results demonstrate that, in a wide temperature range, the proton conductivity of the films reaches a maximum atx= 1.5. The activation energy of conductivity in the films, equal to 0.1–0.2 eV at low temperatures, rises upon partial dehydration above 100°C. The possible mechanisms of proton formation and transport are discussed.
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Leonidov, I.A., Volkov, V.L., Zakharova, G.S. et al. Proton Conductivity in H2 – x (NH4) x V9Mo3O32.5 – δ · nH2O Xerogel Films. Inorganic Materials 38, 1178–1182 (2002). https://doi.org/10.1023/A:1020983003666
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DOI: https://doi.org/10.1023/A:1020983003666