Abstract
Addition of bromine and potassium dihaloiodates(i) to 2-alkyl-2-azabicyclo[2.2.1]hept-5-enes and 2-alkyl-2-azabicyclo[2.2.2]oct-5-enes affords quaternary ammonium salts containing the aziridine ring and the polyhalide anion. The possibility of using these salts for the synthesis of 6-substituted 2-alkyl-2-azabicyclo[2.2.1]heptanes has been shown.
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Sosonyuk, S.E., Bulanov, M.N., Leshcheva, I.F. et al. Halogenation of 2-alkyl-2-azabicycloalkenes as a method for the synthesis of stable aziridinium salts of a new class. Russian Chemical Bulletin 51, 1254–1261 (2002). https://doi.org/10.1023/A:1020904630518
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DOI: https://doi.org/10.1023/A:1020904630518