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Correlation between the Anisotropy of the Electronic Polarizability of Molecules and the Anisotropy of the van der Waals Atomic Radii

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Abstract

A procedure was developed for determining the anisotropy of the van der Waals atomic radii of halogens, hydrogen, oxygen, and sulfur in polyatomic molecules from the experimental characteristics of the anisotropic electronic polarizability of these molecules. The results are consistent with the published van der Waals radii determined by independent procedures.

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REFERENCES

  1. Kitaigorodskii, A.I., Khotsyanova, T.L., and Struchkov, Yu.T., Zh. Fiz. Khim., 1953, vol. 27, no. 6, pp. 780–781.

    Google Scholar 

  2. Nyburg, S.C. and Faerman, C.H., Acta Crystallogr., Sect. B, 1985, vol. 41, no. 4, pp. 274–279.

    Google Scholar 

  3. Batsanov, S.S., Struct. Chem., 1999, vol. 10, no. 6, pp. 395–400.

    Google Scholar 

  4. Batsanov, S.S., Struct. Chem., 2000, vol. 11, nos. 2–3, pp. 173–180.

    Google Scholar 

  5. Bader, R.F.W., Carroll, M.T., Cheeseman, J.R., and Chang, C., J. Am. Chem. Soc., 1987, vol. 109, no. 26, pp. 7968–7979.

    Google Scholar 

  6. Ishikawa, M., Ikuta, S., Katada, M., and Sano, H., Acta Crystallogr., Sect. B, 1990, vol. 46, no. 5, pp. 592–598.

    Google Scholar 

  7. Badenhoop, J.K. and Weinhold, F., J. Chem. Phys., 1997, vol. 107, no. 14, pp. 5422–5432.

    Google Scholar 

  8. Batsanov, S.S., Strukturnaya khimiya. Fakty i zavisimosti (Structural Chemistry. Facts and Relationships), Moscow: Mosk. Gos. Univ., 2000.

    Google Scholar 

  9. Chalasinski, G. and Gutowski, M., Chem. Rev., 1988, vol. 88, no. 6, pp. 943–962.

    Google Scholar 

  10. Aquilanti, V., Ascenzi, D., Bartolomei, M., Cappelletti, D., Cavalli, S., Vitores, M. de C., and Pirani, F., J. Am. Chem. Soc., 1999, vol. 121, no. 46, pp. 10 794–10 802.

    Google Scholar 

  11. Batsanov, S.S., J. Chem. Soc., Dalton Trans., 1998, no. 5, pp. 1541–1545.

  12. Alms, G.R., Burnham, A.K., and Flygare, W.H., J. Chem. Phys., 1975, vol. 63, no. 8, pp. 3321–3326.

    Google Scholar 

  13. Fowler, P.W. and Diercksen, G.H.F., Chem. Phys. Lett., 1990, vol. 167, nos. 1–2, pp. 105–110.

    Google Scholar 

  14. Tammer, R. and Huttner, W., Mol. Phys., 1994, vol. 83, no. 3, pp. 579–590.

    Google Scholar 

  15. Keir, R.I., Lamb, D.W., Ritchie, G.L.D., and Watson, J.N., Chem. Phys. Lett., 1997, vol. 279, nos. 1–2, pp. 22–28.

    Google Scholar 

  16. Peebles, R.A. and Kuczkowski, R.L., J. Phys. Chem. A, 2000, vol. 104, no. 21, pp. 4968–4975.

    Google Scholar 

  17. Dutton, C.C., Dows, D.A., Eikey, R., Evans, S., and Beaudet, R.A., J. Phys. Chem. A, 1998, vol. 102, no. 35, pp. 6904–6909.

    Google Scholar 

  18. Batsanov, S.S., Koord. Khim., 1998, vol. 24, no. 7, pp. 483–487.

    Google Scholar 

  19. Batsanov, S.S., Strukturnaya refraktometriya (Structural Refractometry), Moscow: Vysshaya Shkola, 1976.

    Google Scholar 

  20. Keir, R.I. and Ritchie, G.L.D., Chem. Phys. Lett., 1998, vol. 290, nos. 4–6, pp. 409–414.

    Google Scholar 

  21. Waber, J.T. and Cromer, D.T., J. Chem. Phys., 1965, vol. 42, no. 12, pp. 4116–4123.

    Google Scholar 

  22. Batsanov, S.S., J. Mol. Struct. (THEOCHEM), 1999, vol. 468, pp. 151–159.

    Google Scholar 

  23. Baur, W.H., Acta Crystallogr., Sect. B, 1992, vol. 48, no. 5, pp. 745–746.

    Google Scholar 

  24. Allen, G.W. and Aroney, M.J., J. Chem. Soc., Faraday Trans. 2, 1989, vol. 85, no. 3, pp. 247–249.

    Google Scholar 

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  1. Russian Research Institute of Physicotechnical and Radiotechnical Measurements, Mendeleevo, Moscow oblast, Russia

    S. S. Batsanov

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  1. S. S. Batsanov
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Batsanov, S.S. Correlation between the Anisotropy of the Electronic Polarizability of Molecules and the Anisotropy of the van der Waals Atomic Radii. Russian Journal of General Chemistry 72, 1153–1156 (2002). https://doi.org/10.1023/A:1020890604691

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