Skip to main content
SpringerLink
Log in

Effect of the rhenium additive to VOx/TiO2 and MoOx/TiO2 catalysts on their properties in oxidative dehydrogenation of propane

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

VOx/TiO2 and MoOx/TiO2 catalysts with the addition of Re (Re/V or Mo = 0.5) were synthetized and tested in oxidative dehydrogenation of propane and in reduction by propane. XPS measurements showed depletion of the surface in Re. The Re additive does not affect the total conversion of propane, but increases the selectivity to propene. The effect is more pronounced for the MoOx/TiO2 catalyst. The increase in the selectivity to propene is accompanied with the increase in the reducibility of the catalysts.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. H. Liu, E.M. Gaigneaux, H. Imoto: Appl. Catal. A: Gen., 202, 251 (2000).

    Google Scholar 

  2. E.M. Gaigneaux, H. Liu, H. Imoto: Topics Catal., 11/12, 185 (2000).

    Google Scholar 

  3. H.H. Kung: Adv. Catal., 40, 1 (1994).

    Google Scholar 

  4. S. Albonetti, F. Cavani, F. Trifirò: Catal. Rev. Sci. Eng., 38(4), 413 (1996).

    Google Scholar 

  5. F. Cavani, F. Trifiro: Catal. Today, 36, 431 (1997).

    Google Scholar 

  6. B. Grzybowska, P. Mekss, R. Grabowski, K. Weisło, Barbaux, L. Gengembre: Stud. Surf. Sci. Catal., 82, 151 (1994).

    Google Scholar 

  7. R. Grabowski, B. Grzybowska, K. Samson, J. Słoczyński, Stoch, K. Weisło: Appl. Catal. A: General, 125, 129 (1995).

    Google Scholar 

  8. R. Grabowski, B. Grzybowska, K. Weisło: Polish J. Chem., 68, 1803 (1994).

    Google Scholar 

  9. B. Grzybowska–Świerkosz: Topics Catal., 11/12, 23 (2000).

    Google Scholar 

  10. J. Stoch, A. Stoch, M. Mikołajczyk, A. Brożek: Polish J. Chem., 72, 2609 (1998).

    Google Scholar 

  11. J. Stoch, M. Mikołajczyk: unpublished data.

  12. ICPDS–International Centre for Diffraction Data, 1995, nr 20–1380, 20–1381, 41–141.

  13. J. Słoczyński, M. Rembelska, B. Grzybowska: in preparation.

  14. A.A. Lemonidou, L. Nalbandian, I.A. Vasalos: Catal. Today, 61, 333 (2000).

    Google Scholar 

  15. J.M. López Nieto, R. Coenraads, A. Dejoz, M.I. Vazquez: Stud. Surf. Sci. Catal., 110, 443 (1997).

    Google Scholar 

  16. E.A. Mamedov, V. Cortes Corberan: Appl. Catal., 127, 1 (1995).

    Google Scholar 

  17. C.T. Au, W.D. Zhang, H.L. Wan: Catal. Lett., 37, 241 (1996).

    Google Scholar 

  18. X. Gao, P. Ruiz, Q. Xin, X. Guo, B. Delmon: Catal. Lett., 23, 321 (1994).

    Google Scholar 

  19. R.X. Valenzuela, J.L.G. Fierro, V.C. Corberan, E.A. Mamedov: Catal. Lett., 40, 223 (1996).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Polish Academy of Sciences, Institute of Catalysis and Surface Chemistry, 30-239, Kraków, ul. Niezapominajek 8, Poland

    Katarzyna Samson, Anna Klisińska, Irena Gressel & Barbara Grzybowska

Authors
  1. Katarzyna Samson
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Anna Klisińska
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Irena Gressel
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Barbara Grzybowska
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Samson, K., Klisińska, A., Gressel, I. et al. Effect of the rhenium additive to VOx/TiO2 and MoOx/TiO2 catalysts on their properties in oxidative dehydrogenation of propane. Reaction Kinetics and Catalysis Letters 77, 309–315 (2002). https://doi.org/10.1023/A:1020887919167

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1020887919167

Search

Navigation