Abstract
Dependences of the rate of bioelectrocatalytic reduction of oxygen at an electrode with a laccase–Nafion composite on the partial oxygen pressure are obtained in a wide potential range. The saturation concentration by oxygen for this enzyme electrode is 0.98 mM and the solution stirring tells only at low partial oxygen pressures. The Michaelis constants and catalytic constants are compared in conditions bioelectrocatalysis and enzymic catalysis.
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REFERENCES
Bespamyatnov, G.P. and Krotov, Yu.A., Predel'nodopustimye kontsentratsii khimicheskikh veshchestv v okruzhayushchei srede: Spravochnik (Maximum Permissible Concentrations of Chemical Substances in the Environment: A Reference Book), Leningrad: Khimiya, 1985.
Sanitarnye pravila i normy 2.1.4.599-96: “Pit'evaya voda. Gigienicheskie trebovaniya k kachestvu vody tsentralizovannykh sistem pit'evogo vodosnabzheniya. Kontrol' kachestva vody” (Public Health Regulations 2.1.4.599-96, “Drinking Water: Sanitary Requirements to the Quality of Mains Water: Water Quality Control), Moscow: Goskomitet Sanitarno-Epidemiologicheskogo Nadzora Rossiiskoi Federatsii, 1996 (introduced January 1, 1998).
Ruzgas, T., Gorton, L., Emneus, J., and Marko-Varga, G., Anal. Chim. Acta, 1995, vol. 311, p. 245.
Gegeshidze, L.V., Efremov, B.N., Zhutaeva, G.V., and Tarasevich, M.R., Elektrokhimiya, 1999, vol. 35, p. 1365.
Bonakdar, M., Vilchez, J.L., and Motolla, H.A., J. Electroanal. Chem., 1989, vol. 266, p. 50.
Kotte, H., Grundig, B., Vorlop, K.-D., et al., Anal. Chim. Acta, 1995, vol. 67, p. 65.
Yaropolov, A.I., Kharibin, A.N., Emneus, J., et al., Anal. Chim. Acta, 1995, vol. 308, p. 138.
Ghindilis, A.L., Gavrilova, V.P., and Yaropolov, A.I., Biosens. Bioelectron., 1992, vol. 7, p. 127.
Solomon, E.I., Sundaram, V.M., and Machonkin, T.E., Chem. Rev., 1996, vol. 96, p. 2563.
Tarasevich, M.R., Bogdanovskaya, V.A., and Kuznetsova, L.N., Elektrokhimiya, 2001, vol. 37, p. 969.
Gindilis, A.L., Zhazhina, E.O., Baranov, Yu.A., et al., Biokhimiya, 1988, vol. 53, p. 735.
Yaropolov, A.I., Kharibin, A.N., Emneus, J., et al., Bioelectrochem. Bioenerg., 1996, vol. 40, p. 49.
Watanabe, M., Igarashi, H., and Yosioka, K., Electrochim. Acta, 1995, vol. 40, p. 329.
Bogdanovskaya, V.A., Tarasevich, M.R., and Gavrilova, E.F., Elektrokhimiya, 1986, vol. 22, p. 724.
Thuesen, M.H., Farver, O., Reinhammar, B., and Ulstrup, J., Acta Chem. Scand., 1998, vol. 52, p. 556.
Petushkova, E.V., Vvedenie v kinetiku fermentativnykh reaktsii (An Introduction to the Kinetics of Enzymic Reactions), Moscow: Mosk. Gos. Univ., 1972.
Stepanova, E.V., Cand. Sci. (Biol.) Dissertation, Moscow: Bach Institute of Biochemistry, Russian Academy of Sciences, 1999.
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Osina, M.A., Bogdanovskaya, V.A. & Efremov, B.N. Effect of Partial Pressure of Oxygen on Its Bioelectrocatalytic Reduction at a Laccase–Nafion Composite. Russian Journal of Electrochemistry 38, 1082–1086 (2002). https://doi.org/10.1023/A:1020695401751
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DOI: https://doi.org/10.1023/A:1020695401751