Skip to main content
Log in

Distillation of Nonideal Ternary Zeotropic Mixtures in Two-Feed Columns

  • Published:
Theoretical Foundations of Chemical Engineering Aims and scope Submit manuscript

Abstract

The continuous distillation of ternary nonideal zeotropic mixtures in two-feed columns is modeled. The results obtained are compared with the results of continuous distillation in one-feed columns. The topography of the field of relative-volatility coefficients is considered for various types of zeotropic systems. Possible separation flow sheets are presented for various distillation processes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. Petlyuk, F.B., Vinogradova, E.I., Maiskii, V.I., and Serafimov, L.A., Feasible Splits of Azeotropic Mixtures in Simple and Complex Columns Operated at Minimum Reflux, Tezisy V Vsesoyuznoi konferentsii po teorii i praktike rektifikatsii (Proc. V All-Union Conf. on the Theory and Practice of Distillation), Severodonetsk, 1984, part 1, p. 8.

  2. Kiva, V.N., Timofeev, V.S., Vizhesingkhe, A.D.M.Ch., and Vu Tam Khyue, Separating Binary Azeotropes by Distillation with a Low-Boiling Azeotropic Agent, Tezisy V Vsesoyuznoi konferentsii po teorii i praktike rektifikatsii (Proc. V All-Union Conf. on the Theory and Practice of Distillation), Severodonetsk, 1984, part 1, p. 19.

  3. Kogan, V.B., Azeotropnaya i ekstraktivnaya rektifikatsiya (Azeotropic and Extractive Distillation), Leningrad: Khimiya, 1971.

    Google Scholar 

  4. Kazas, M.S., Thermodynamic and Topological Analysis for Choosing Azeotropic and Extractive Distillation Flowsheets As Applied to Alcohol Dehydration, Abstract of Cand. Sci. (Eng.) Dissertation, Moscow: Moscow Inst. of Fine Chemical Technology im. M.V. Lomonosova, 1972.

    Google Scholar 

  5. Timofeev, V.S., Polyakova, E.V., Khanina, E.P., and Pavlenko, T.G., Autoextractive Distillation As a Way of Eliminating the Limitations Arising from the Structure of the Liquid–Vapor Equilibrium Diagram, Tezisy IV Vsesoyuznoi konferentsii po teorii i praktike rektifikatsii (Proc. IV All-Union Conf. on the Theory and Practice of Distillation), Ufa, 1978, p. 298.

  6. Khanina, E.P., Pavlenko, T.G., Bogatyuk, L.A., and Timofeev, V.S., Studies on Autoextractive Distillation, Zh. Prikl. Khim. (Leningrad), 1978, vol. 52, no. 10, p. 2657.

    Google Scholar 

  7. Khanina, E.P., Effect of the Phase-Diagram and Recycle Structures on the Separation Flowsheets, Abstract of Cand. Sci. (Eng.) Dissertation, Moscow: Moscow Inst. of Fine Chemical Technology im. M.V. Lomonosova, 1978.

    Google Scholar 

  8. Kiva, V.N. and Kirichenko, G.A., Distillation in Two-Feed Columns, Neftekhimicheskie protsessy v mnogofaznykh sistemakh (Petrochemical Processes in Multiphase Systems), Moscow: TsNIITENeftekhim, 1980, p. 114.

  9. Vidzhisingkhe Adikari, Complexes of Distillation Techniques for Solvent Regeneration, Cand. Sci. (Eng.) Dissertation Moscow: Moscow Inst. of Fine Chemical Technology im. M.V. Lomonosova, 1985.

    Google Scholar 

  10. Marchenko, I.M., Distillation Process Design for the Recovery of Organic Solvents from Their Aqueous Mixtures in the Manufacture of Video Tapes, Cand. Sci. (Eng.) Dissertation, Barnaul: Altai Polytechnical Inst., 1987.

    Google Scholar 

  11. Frolkova, A.K., Pavlenko, T.G., and Timofeev, V.S., Estimating the Flow Rate of the Separating Agent in Extractive and Autoextractive Distillation, Zh. Prikl. Khim. (Leningrad), 1987, vol. 61, no. 9, p. 631.

    Google Scholar 

  12. Pirog, L.A., Frolkova, A.K., Pavlenko, T.G., et al., Optimizing the Separation of Nonideal Mixtures, Zh. Prikl. Khim. (Leningrad), 1988, vol. 62, no. 9, p. 2037.

    Google Scholar 

  13. Pirog, L.A., Frolkova, A.K., Pavlenko, T.G., et al., Optimizing the Separation of Nonideal Mixtures, Zh. Prikl. Khim. (Leningrad), 1988, vol. 62, no. 9, p. 2144.

    Google Scholar 

  14. Khanina, E.P., Yusef, D.D., and Kiseleva, O.V., Flow Rate of the Separating Agent As a Function of the Original Mixture Composition in Extractive Distillation, Zh. Prikl. Khim. (Leningrad), 1988, vol. 62, no. 9, p. 2167.

    Google Scholar 

  15. Khristenko, M.S., Process Design for the Extractive Distillation Recovery of Solvents from Heterogeneous Polyazeotropic Mixtures, Cand. Sci. (Eng.) Dissertation, Moscow: Moscow Inst. of Fine Chemical Technology im. M.V. Lomonosova, 1988.

    Google Scholar 

  16. Wahnschafft, O.M. and Westerberg, A.W., The Product Composition Regions of Azeotropic Distillation Columns. 2. Separability in Two-Feed Columns and Entrainer Selection, Ind. Eng. Chem. Res., 1993, vol. 32, no. 6, p. 1108.

    Google Scholar 

  17. Lee, F.-M. and Gentry, J.C., Don't Overlook Extractive Distillation, Chem. Eng. Prog., 1997, no. 10, p. 56.

  18. Petlyuk, F.B. and Danilov, R.Yu., Sharp Distillation of Azeotropic Mixtures in a Two-Feed Column, Teor. Osn. Khim. Tekhnol., 1999, vol. 33, no. 3, p. 259.

    Google Scholar 

  19. Orlova, E.V., Zhvanetskii, I.B., and Reshetov, S.A., Mathematical Modeling of Diagrams of K-Ordered Regions for Ternary Nonideal Zeotropic Mixtures, Teor. Osn. Khim. Tekhnol., 1997, vol. 31, no. 4, p. 313.

    Google Scholar 

  20. Orlova, E.V., Reshetov, S.A., and Zhvanetskii, I.B., Mathematical Modeling of Diagrams of K-Ordered Regions for Ternary Azeotropic Mixtures, Teor. Osn. Khim. Tekhnol., 1997, vol. 31, no. 6, p. 613.

    Google Scholar 

  21. Zharov, V.T. and Serafimov, L.A., Fizikokhimicheskie osnovy rektifikatsii (Physicochemical Foundations of Distillation), Leningrad: Khimiya, 1975.

    Google Scholar 

  22. Zhvanetskii, I.B., Reshetov, S.A., and Sluchenkov, V.Yu., Classification of K-Ordered Regions in the Distillation-Line Diagram of a Ternary Zeotropic System, Zh. Fiz. Khim., 1988, vol. 62, no. 7, p. 1944.

    Google Scholar 

  23. Reshetov, S.A., Continuous Distillation of Ternary Mixtures with C-and S-Shaped Lines of Conjugate Tie Lines and Inverted Tie Lines, Teor. Osn. Khim. Tekhnol., 2000, vol. 34, no. 5, p. 514.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Reshetov, S.A. Distillation of Nonideal Ternary Zeotropic Mixtures in Two-Feed Columns. Theoretical Foundations of Chemical Engineering 36, 447–457 (2002). https://doi.org/10.1023/A:1020669627482

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1020669627482

Keywords

Navigation