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Layered-Double-Hydroxide-Supported Pd(TPPTS)2Cl2: A New Heterogeneous Catalyst for Heck Arylation of Olefins

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Abstract

The Pd(TPPTS)2Cl2 (TPPTS: triphenylphosphine trisulfonate, sodium salt) complex is immobilized on layered double hydroxides by the ion-exchange method. This heterogeneous catalyst is successfully used in Heck arylation of olefins. The catalyst can be recycled several times with almost consistent activity.

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References

  1. E. Kuntz, Chemtech. 17 (1987) 570; (b) W.A. Hermann and C.W. Kohlpaintner, Angew. Chem. Int. Ed. Engl. 32 (1993) 1524.

    Google Scholar 

  2. J.M. Grosselin, C. Mercier, G. Allmang and F. Grass, Organometallics 10 (1991) 2126.

    Google Scholar 

  3. G.T. Brink, I.W.C.E. Arends and R.A. Sheldon, Science 287 (2000) 1636.

    Google Scholar 

  4. T. Thorpe, S.M. Brown, J. Crosby, S. Fitzjohn, J.P. Muxworthy and J.M.J. Williams. Tetrahedron Lett. 41 (2000) 4503.

    Google Scholar 

  5. G. Wullner, H. Jansch, S. Kannenberg, F. Schubert and G. Boche, Chem. Commun. (1998) 1509.

  6. J.P. Arhancet, M.E. Davis, J.S. Merola and B.E. Hanson, Nature 339 (1989) 454.

    Google Scholar 

  7. I. Guo, B.E. Hanson, I. Toth and M.E. Davis, J. Organomet. Chem. 403 (1991) 221; (b) J.P. Arhancet, M.E. Davis, J.S. Merola and B.E. Hanson, J. Catal. 121 (1990) 327.

    Google Scholar 

  8. E. Fache, C. Mercier, N. Pagnier, B. Despeyroux and P. Panster, J. Mol. Catal. 79 (1993) 117.

    Google Scholar 

  9. L. Tonks, M.S. Anson, K. Hellgardt, A.R Mirza, D.F Thompson and J.M.J. Williams, Tetrahedron Lett. 38(24) (1997) 4319.

    Google Scholar 

  10. A. de Meijere and F.E. Meyer, Angew. Chem. 106 (1994) 2473; (b) W. Cabri and I. Candiani, Acc. Chem. Res. 28 (1995) 2.

    Google Scholar 

  11. F. Trifiro and A. Vaccari, in: Comprehensive Supramolecular Chemistry, Vol. 7 (Pergamon, Elsevier Science, Oxford, 1996), p. 251.

    Google Scholar 

  12. B.M. Choudary, M.L. Kantam, A. Rahman, Ch.V. Reddy and K.K. Rao, Angew. Chem. Int. Ed. Engl. 40 (2001) 763; (b) M.L. Kantam, B.M. Choudary, Ch.V. Reddy, K.K. Rao and F. Figueras, Chem. Commun. 40 (1998) 763; (c) B.M. Choudary, M.L. Kantam, B. Kavita, Ch.V. Reddy, K.K. Rao and F. Figueras, Tetrahedron Lett. 39 (1998) 3555; (d) B.M. Choudary, N.S. Choudari, M. Lakshmi Kantam and K.V. Raghavan, J. Am. Chem. Soc. 123 (2001) 9220.

    Google Scholar 

  13. B. Sels, D. De Vos, M. Buntinx, F. Pierard, A. Kirsch-De Mesmaeker and P.A. Jacobs, Nature 400 (1999) 855; (b) F.V. Laar, D. De Vos, D. Vanoppen, B.F. Sels, P.A. Jacobs, A. Del Guerzo, F. Pierard and A. Kirsch-De Mesmaeker, Chem. Commun. (1998) 267; (c) S. Miyata, Clays and Clay Minerals 23 (1975) 369.

    Google Scholar 

  14. T. Bartik, B. Bartik, B.E. Hanson, T. Glass and W. Bebout, Inorg. Chem. 31 (1992) 2667.

    Google Scholar 

  15. H. Jiang, Y. Xu, S. Liao, D. Yu, H. Chen and X. Li, J. Mol. Catal. A 130 (1998) 79.

    Google Scholar 

  16. M. Julia, M. Duteil, C. Grard and E. Kuntz, Bull. Soc. Chim. Fr. (1973) 2791; (b) F. Zhao, B.M. Bhanage, M. Shirai and M. Arai, Chem. Eur. J. 6 (2000) 843.

  17. B.M. Bhange, F. Zhao, M. Shirai and M. Arai, J. Mol. Catal. 145 (1999) 69; (b) B.M. Bhange, F. Zhao, M. Shirai and M. Arai, Catal. Lett. 54 (1998) 195.

    Google Scholar 

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Choudary, B., Lakshmi Kantam, M., Mahender Reddy, N. et al. Layered-Double-Hydroxide-Supported Pd(TPPTS)2Cl2: A New Heterogeneous Catalyst for Heck Arylation of Olefins. Catalysis Letters 82, 79–83 (2002). https://doi.org/10.1023/A:1020596209386

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