Abstract
The Pd(TPPTS)2Cl2 (TPPTS: triphenylphosphine trisulfonate, sodium salt) complex is immobilized on layered double hydroxides by the ion-exchange method. This heterogeneous catalyst is successfully used in Heck arylation of olefins. The catalyst can be recycled several times with almost consistent activity.
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E. Kuntz, Chemtech. 17 (1987) 570; (b) W.A. Hermann and C.W. Kohlpaintner, Angew. Chem. Int. Ed. Engl. 32 (1993) 1524.
J.M. Grosselin, C. Mercier, G. Allmang and F. Grass, Organometallics 10 (1991) 2126.
G.T. Brink, I.W.C.E. Arends and R.A. Sheldon, Science 287 (2000) 1636.
T. Thorpe, S.M. Brown, J. Crosby, S. Fitzjohn, J.P. Muxworthy and J.M.J. Williams. Tetrahedron Lett. 41 (2000) 4503.
G. Wullner, H. Jansch, S. Kannenberg, F. Schubert and G. Boche, Chem. Commun. (1998) 1509.
J.P. Arhancet, M.E. Davis, J.S. Merola and B.E. Hanson, Nature 339 (1989) 454.
I. Guo, B.E. Hanson, I. Toth and M.E. Davis, J. Organomet. Chem. 403 (1991) 221; (b) J.P. Arhancet, M.E. Davis, J.S. Merola and B.E. Hanson, J. Catal. 121 (1990) 327.
E. Fache, C. Mercier, N. Pagnier, B. Despeyroux and P. Panster, J. Mol. Catal. 79 (1993) 117.
L. Tonks, M.S. Anson, K. Hellgardt, A.R Mirza, D.F Thompson and J.M.J. Williams, Tetrahedron Lett. 38(24) (1997) 4319.
A. de Meijere and F.E. Meyer, Angew. Chem. 106 (1994) 2473; (b) W. Cabri and I. Candiani, Acc. Chem. Res. 28 (1995) 2.
F. Trifiro and A. Vaccari, in: Comprehensive Supramolecular Chemistry, Vol. 7 (Pergamon, Elsevier Science, Oxford, 1996), p. 251.
B.M. Choudary, M.L. Kantam, A. Rahman, Ch.V. Reddy and K.K. Rao, Angew. Chem. Int. Ed. Engl. 40 (2001) 763; (b) M.L. Kantam, B.M. Choudary, Ch.V. Reddy, K.K. Rao and F. Figueras, Chem. Commun. 40 (1998) 763; (c) B.M. Choudary, M.L. Kantam, B. Kavita, Ch.V. Reddy, K.K. Rao and F. Figueras, Tetrahedron Lett. 39 (1998) 3555; (d) B.M. Choudary, N.S. Choudari, M. Lakshmi Kantam and K.V. Raghavan, J. Am. Chem. Soc. 123 (2001) 9220.
B. Sels, D. De Vos, M. Buntinx, F. Pierard, A. Kirsch-De Mesmaeker and P.A. Jacobs, Nature 400 (1999) 855; (b) F.V. Laar, D. De Vos, D. Vanoppen, B.F. Sels, P.A. Jacobs, A. Del Guerzo, F. Pierard and A. Kirsch-De Mesmaeker, Chem. Commun. (1998) 267; (c) S. Miyata, Clays and Clay Minerals 23 (1975) 369.
T. Bartik, B. Bartik, B.E. Hanson, T. Glass and W. Bebout, Inorg. Chem. 31 (1992) 2667.
H. Jiang, Y. Xu, S. Liao, D. Yu, H. Chen and X. Li, J. Mol. Catal. A 130 (1998) 79.
M. Julia, M. Duteil, C. Grard and E. Kuntz, Bull. Soc. Chim. Fr. (1973) 2791; (b) F. Zhao, B.M. Bhanage, M. Shirai and M. Arai, Chem. Eur. J. 6 (2000) 843.
B.M. Bhange, F. Zhao, M. Shirai and M. Arai, J. Mol. Catal. 145 (1999) 69; (b) B.M. Bhange, F. Zhao, M. Shirai and M. Arai, Catal. Lett. 54 (1998) 195.
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Choudary, B., Lakshmi Kantam, M., Mahender Reddy, N. et al. Layered-Double-Hydroxide-Supported Pd(TPPTS)2Cl2: A New Heterogeneous Catalyst for Heck Arylation of Olefins. Catalysis Letters 82, 79–83 (2002). https://doi.org/10.1023/A:1020596209386
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DOI: https://doi.org/10.1023/A:1020596209386