Skip to main content
Log in

Synthesis of Esters Under Microwave Irradiation Using Heteropoly Acids as Catalysts

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

A practical and simple technique for synthesis of esters was developed by using heteropoly acid as catalyst under microwave irradiation in the absence of organic solvents. Alcohols were easily and selectively converted to their acetates and benzoates with excellent yields (≥98%), and in very short time (∼5 min), as environmentally benign.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. March, Advanced Organic Chemistry, 4th edition (Wiley, New York, 1992) p. 393.

    Google Scholar 

  2. M.B. Smith, Organic Synthesis (McGraw-Hill, New York, 1994) p. 638.

    Google Scholar 

  3. R.S. Varma, Green Chem. 1 (1999) 43.

    Google Scholar 

  4. T. Okuhara, N. Mizuno and M. Misono, Adv. Catal. 41 (1996) 113.

    Google Scholar 

  5. I.V. Kozhevnikov, Chem. Rev. 98 (1998) 171.

    Google Scholar 

  6. M. Misono, I. Ono, G. Koyano and A. Aoshima, Pure Appl. Chem. 72 (2000) 1305.

    Google Scholar 

  7. M. Misono, Chem. Commun. 13 (2001) 1141.

    Google Scholar 

  8. Y. Izumi and K. Urabe, Chem. Lett. (1981) 663.

  9. M. Misono, Catal. Lett. 12 (1992) 63.

    Google Scholar 

  10. Y. Izumi, M. Ono, M. Ogawa and K. Urabe, Chem. Lett. (1993) 825.

  11. C. Hu, M. Hashimoto, T. Okuhara and M. Misono, J. Catal. 143 (1993) 437.

    Google Scholar 

  12. M.J. Verhoef, P.J. Kooyman, J.A. Peters, H. van Bekkum, Micropor. Mesopor. Mat. 27 (1999) 365.

    Google Scholar 

  13. S. Deshayes, M. Liagre, A. Loupy, J.-L. Luche and A. Petit, Tetrahedron 55 (1999) 10851.

    Google Scholar 

  14. A. Loupy, A. Petit, J. Hamelin, F. Texier-Boullet, P. Jacquault and D. Mathe, Synthesis-Stuttgart 9 (1998) 1213.

    Google Scholar 

  15. C.S. Cundy, Collect. Czech. Chem. C 63 (1998) 1699.

    Google Scholar 

  16. S.A. Galema, Chem. Soc. Rev. 26 (1997) 233.

    Google Scholar 

  17. R. Gedye, F. Smith, K. Westawey, H. Ali, L. Baldisera, L. Laberge, and J. Roussell, Tetrahedron Lett. 27 (1986) 279.

    Google Scholar 

  18. A. Loupy, A. Petit, M. Ramdani and C. Yvanaeff, Can. J. Chem. 71 (1993) 90.

    Google Scholar 

  19. G. Majetich and R. Hicks, Res. Chem. Intermed. 20 (1994) 61.

    Google Scholar 

  20. A. Loupy, P. Pigeon and M. Ramdani, Tetrahedron 52 (1996) 6705.

    Google Scholar 

  21. G. Bratulescu, Y. Le Bigot and M. Delmas, Synth. Commun. 30 (2000) 171.

    Google Scholar 

  22. G. Pipus, I. Plazl and T. Koloini, Chem. Eng. J. 76 (2000) 239.

    Google Scholar 

  23. X.J. Fan, K. Yuan, C. Hao, N. Li, G. Tan and X. Yu, Org. Prep. Proced. Int. 32 (2000) 287.

    Google Scholar 

  24. Z.B. Zhang, L.X. Zhou, M. Zhang, H. Wu and Z.J. Chen, Synth. Commun. 31 (2001) 2435.

    Google Scholar 

  25. B. Gümgüm and O. Akba, Syn. React. Inorg. Met. 23 (1993) 963.

    Google Scholar 

  26. O. Akba, F. Güzel, K. Yurdakoç, B. Gümgüm and Z. Tez, Syn. React. Inorg. Met. 27 (1997) 1399.

    Google Scholar 

  27. B. Gümgüm, N. Biricik and A. Baysal, Phosphorus Sulphur 167 (2000) 111.

    Google Scholar 

  28. B. Gümgüm and G. Öztürk, Chem. Spec. Bioavailab. 13 (2001) 25.

    Google Scholar 

  29. G. Öztürk and B. Gümgüm, in preparation.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Öztürk, G., Gümgüm, B. & Akba, O. Synthesis of Esters Under Microwave Irradiation Using Heteropoly Acids as Catalysts. Catalysis Letters 82, 233–235 (2002). https://doi.org/10.1023/A:1020579231020

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1020579231020

Navigation