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Hyperfine Study on Mechanically Alloyed Fe–Mn Systems

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Abstract

High-energy ball milling of Fe–Mn elemental powder mixtures has been carried out for different Mn concentrations, ranging from 0 to 90%. Mössbauer spectroscopy of 57Fe and perturbed angular correlations with 111In – implanted at 400 keV into pills made from the milled powders – have been used to investigate the structure of the milled samples. Clear changes of the hyperfine spectra occur at Mn concentrations of 15–20% and above 70%, indicating extended concentration ranges of α-Fe and γ-Fe(Mn), compared to the equilibrium phase diagram. Detailed information on additional lower hyperfine fields due to nearest neighbor Mn atoms has been obtained in the α-Fe phase containing up to 20% Mn .

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Authors and Affiliations

  1. II. Physikalisches Institut, Universität Göttingen, Bunsenstr. 7-9, D-37073, Göttingen, Germany

    M. Uhrmacher & A. Kulinska

  2. Henryk Niewodniczanski Institute of Nuclear Physics, ul. Razikowskiego 152, 31-342, Krakow, Poland

    A. Kulinska

  3. Semenov Inst. of Phys.Chem., Russian Academy of Science, Kosygina str. 4, 117977, Moscow, Russia

    Yu. V. Baldokhin

  4. Dept. of Phys. Chem., Moscow State Steel and Alloys Inst., Leninsky prosp. 4, 117936, Moscow, Russia

    V. V. Tcherdyntsev & S. D. Kaloshkin

  5. INFM, Unità di Padova, Settore Materiali, DIM, Univ. di Padova, v. Marzolo 9, 35131, Padova, Italy

    A. Maddalena & G. Principi

Authors
  1. M. Uhrmacher
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  2. A. Kulinska
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  3. Yu. V. Baldokhin
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  4. V. V. Tcherdyntsev
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  5. S. D. Kaloshkin
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  6. A. Maddalena
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  7. G. Principi
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Uhrmacher, M., Kulinska, A., Baldokhin, Y.V. et al. Hyperfine Study on Mechanically Alloyed Fe–Mn Systems. Hyperfine Interactions 136, 327–332 (2001). https://doi.org/10.1023/A:1020577523577

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