Abstract
Oligo[aromatic diimidoselenium] (PADIS) is prepared from the reaction of the disubstituted aromatic compounds, namely, 1,4-phenylenediamine, 4,4′-thiodianiline, 1,1′-biphenylene-4,4′-diamine, and 2,2′-dithiodianiline, with selenium dioxide in refluxing absolute ethanol. The four materials are investigated by elemental analysis, electronic spectra, Fourier Transform-infrared spectroscopy, and [1H]NMR spectroscopy. The DC electrical conductivity variation with temperature in the range 300–500 K of the materials after annealing for 24 h at 100°C and after doping with 10% I2 is determined for comparison.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
D. Jerome, A. Mazaud, M. Ribault, and K. Bechgaard, J. Phys. Lett. L-95, 41 (1980).
S. S. P. Parkin, E. M. Engler, R. R. Schumaker, R. Lagier, V. Y. Lee, G. Voiron, K. Carneiro, G. C. Scott, and R. L. Greene, J. Phys. Paris Colloq. C3, 791 (1983).
E. B. Yagubskii, I. F. Shchegolev, V. N. Laukhin, P. S. Kononovich, A. K. Kartsovnik, A. V. Zvarykina, and L. I. Buraov, GETP Lett. 39, 12 (1984).
D. Liotta, Organoselenium Chemistry (Wiley-Interscience, New York, 1987), pp. 395–409.
D. L. Klayman and W. H. H. Goenther, Organic Selenium Compounds, Their Chemistry and Biology (Wiley-Interscience, New York, 1973), pp. 815–834.
D. J. Sandman, M. Rubner, and Samuelson, J. Chem. Soc. Chem. Commun., p. 1133 (1982).
K.-Y. Jen, N. Benfaremo, M. P. Cava, W.-S Huang, and A. G. MacDiarmid, J. Chem. Soc. Chem. Commun., p. 633 (1983).
F. Wudl, E. T. Zellers, and D. Nalewajek, J. Org. Chem. 45, 3211 (1980).
C. L. Wilson and D. W. Wilson, Comprehensive Analytical Chemistry, Vol. 1c (Elsevier, New York, 1962), pp. 614–615.
A. El-Shekeil, M. A. Khalid, H. Al-Maydama, and A. Al-Karbooly, Eur. Poly. J. 37, 575 (2001).
M. A. Khalid, A. El-Shekeil, and F. Al-Yusufy, Eur. Poly. J. 37, 1423 (2001).
A. El-Shekeil, H. Al-Maydama, and A. Al-Karbooly, J. Inorg. Organomet. Polym. 7, 121 (1997).
M. Silverstein, G. Bassler, and C. Morril, Spectrometric Identification of Organic Compounds, 4th Ed., (Wiley, New York, 1981), p. 132.
S. H. Ataiw, G. B. El-Hefnawey, and N. T. Abdel Ghany, Ann. Chem. 72, 95 (1982).
G. Y. Chao and J. D. McCullough, Acta Crystall. 14, 40 (1961).
H. Maddox and J. D. McCullough, J. Inorg. Chem. 5, 522 (1966).
R. Pecsoc, L. Shields, T. Cairns, and I. McWilliam, Modern Methods of Chemical Analysis, 2nd Ed. (Wiley, New York, 1976), p. 228.
J. E. Katon, ed., Organic Semiconducting Polymers (Marcel Dekker, New York, 1968).
H. G. Kiess, Conjugated Conducting Polymers (Springer-Verlag, Berlin, 1992).
A. El-Shekeil, F. Al-Yusufy, and S. Saknidy, Poly. Int. 42, 39 (1997).
A. El-Shekeil, M. K. Saad-Addin Hamid, and A. Dheya, Ang. Makromol. Chem. 253, 99 (1997).
H. S. Nalwa, ed., Handbook of Organic Conductive Molecules and Polymers, Vol. 2 (Wiley, Chichester, 1997), pp. 19-22.
N. S. Dance, W. R. McWhinnie, J. Mallaki, and Z. M. Mirzai, J. Organometal. Chem. 198, 131 (1980).
Hiroyuki Nishikawa, et. al., J. Amer. Chem. Soc. 124, 730 (2002).
R. H. Bube, Electronic Properties of Crystalline Solids (Academic Press, London, 1974).
M. Amin, A. El-Shekeil, M. Mounir, and M. Abu El-Ez, Ang. Makromol. Chem. 193, 13 (1991).
A. El-Shekeil, H. Al-Maydama, A. Al-Karbooly, and M. A. Khalid, Polymer 40, 2879 (1999).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
El-Shekeil, A., Abid, K.Y. & Al-Shuja'a, O. Synthesis, Characterization, and Electrical Conductivity of Oligo[aromatic diimidoselenium(IV)]. Journal of Inorganic and Organometallic Polymers 11, 217–234 (2001). https://doi.org/10.1023/A:1020564427095
Issue Date:
DOI: https://doi.org/10.1023/A:1020564427095