Skip to main content
SpringerLink
Log in

Lithium in In2S3

  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

The electrochemical insertion of lithium into β-In2S3 at different concentrations has been investigated by means of γγ-Perturbed Angular Correlations measurements using implanted radioactive 111In nuclei. The study of the hyperfine interactions of the 111Cd nuclei during the decay 111In(EC)111Cd allowed to determine the evolution of the three observed electric field gradients at different temperatures and lithium contents. This study reveals a great difference of behavior between the three indium sites of the structure, and shows the mobility of indium ions and their partial reduction after lithium insertion. In2S3 is good model material to study the properties of more complex materials based on this structure, which may be used as electrodes for lithium-ion batteries.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Dedryvère, R., Denis, S., Pérez Vicente, C., Olivier-Fourcade, J. and Jumas, J.-C., Chem. Mater. 12 (2000), 1439.

    Article  Google Scholar 

  2. Dedryvère, R., Olivier-Fourcade, J., Jumas, J.-C., Denis, S., Lavela, P. and Tirado, J.-L., Electrochimica Acta 46 (2000), 127.

    Article  Google Scholar 

  3. Diehl, R. and Nitsche, R., J. Crystal Growth 28 (1975), 306.

    Article  Google Scholar 

  4. Aldon, L., Uhrmacher, M., Branci, C., Ziegeler, L., Roth, J., Schaaf, P., Metzner, H., Olivier-Fourcade, J. and Jumas, J.-C., Phys. Rev. B 58 (1998), 11 303.

    Article  Google Scholar 

  5. Uhrmacher, M., Aldon, L., Schaaf, P., Metzner, H., Olivier-Fourcade, J. and Jumas, J.-C., Hyp. Interact. 120-121 (1999), 371.

    Article  Google Scholar 

  6. Uhrmacher, M., Pampus, K., Bergmeister, F. J., Purschke, D. and Lieb, K.-P., Nucl. Instr. Meth. B 9 (1985), 234.

    Article  ADS  Google Scholar 

  7. Uhrmacher, M., Neubauer, M., Bolse, W., Ziegeler, L. and Lieb, K.-P., Nucl. Instr. Meth. B 139 (1998), 306.

    Article  ADS  Google Scholar 

  8. Uhrmacher, M., Krishnamurthy, V. V., Lieb, K.-P., Lopez-Garcia, A. and Neubauer, M., Z. Phys. Chem. 206 (1998), 249.

    Google Scholar 

  9. Uhrmacher, M. and Lieb, K.-P., Z. Naturforsch. 55a (2000), 90.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. II. Physikalisches Institut, Universität Göttingen, Bunsenstr. 7-9, D-37073, Göttingen, Germany

    R. Dedryvère, M. Uhrmacher & A. Lohstroh

  2. Laboratoire des Agrégats Moléculaires et des Matériaux Inorganiques, CC15, Université Montpellier 2, F-34095, Montpellier cedex 5, France

    R. Dedryvère, A. Picard-Garcia, J. Olivier-Fourcade & J.-C. Jumas

Authors
  1. R. Dedryvère
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Uhrmacher
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Lohstroh
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. Picard-Garcia
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. J. Olivier-Fourcade
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. J.-C. Jumas
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dedryvère, R., Uhrmacher, M., Lohstroh, A. et al. Lithium in In2S3 . Hyperfine Interactions 136, 479–484 (2001). https://doi.org/10.1023/A:1020554203723

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1020554203723

Search

Navigation