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Mössbauer Study of Hexavalent Iron Compounds

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Abstract

Six crystalline ferrates(VI): K3Na(FeO4)2, K2FeO4, Rb2FeO4, Cs2FeO4, K2Sr(FeO4)2 and BaFeO4, were studied by Mössbauer spectroscopy. Room-temperature spectra of potassium, rubidium and cesium ferrates are single lines, but spectra of barium, potassium–strontium and potassium–sodium ferrates show a presence of quadrupole interactions. Most of these salts display an antiferromagnetic transition with a Néel temperature within 2 to 8 K range.

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Authors and Affiliations

  1. Bauman Moscow State Technical University, 5, 2nd Baumanskaya Street, Moscow, 107005, Russia

    S. K. Dedushenko

  2. Department of Chemistry, Moscow State University, Moscow, 119899, Russia

    Yu. D. Perfiliev

  3. Division of Chemistry & Chemical Engineering, California Institute of Technology, Pasadena, CA, 91125, USA

    M. G. Goldfeld

  4. Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, 91109, USA

    A. I. Tsapin

Authors
  1. S. K. Dedushenko
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  2. Yu. D. Perfiliev
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  3. M. G. Goldfeld
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  4. A. I. Tsapin
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Dedushenko, S.K., Perfiliev, Y.D., Goldfeld, M.G. et al. Mössbauer Study of Hexavalent Iron Compounds. Hyperfine Interactions 136, 373–377 (2001). https://doi.org/10.1023/A:1020541910373

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  • DOI: https://doi.org/10.1023/A:1020541910373

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