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A Novel Catalyst for NO Reduction by CO

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Abstract

A silica-pillared layered niobate (Si-Nb3O8) has been prepared by intercalating layered niobate with NH2(CH2)3Si(OEt)3. The results of XRD and BET measurement showed that the obtained product was a porous material with a high specific surface area and high thermal stability, and its layered structure remained unchanged after treatment with 5 vol% water vapor at 500 °C for 3 h. Using Si-Nb3O8 as support, a 2 wt% Cu/Si-Nb3O8 catalyst was prepared by impregnation of Cu(NO3)2 solution and the catalytic reduction of NO by CO was examined. The results showed that the catalyst had a good activity and selectivity, and the pretreatment of 5 vol% water vapor could obviously improve the conversion of NO reduction, while the selectivity of NO to N2 almost kept unchanged.

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References

  1. J.F. Roth and R.C. Doerr, Ind. Eng. Chem. 53 (1961) 293.

    Google Scholar 

  2. R.A. Baker and R.C. Doer, J. Air Pollut. Control Assoc. 14 (1964) 409.

    Google Scholar 

  3. R.A. Baker and R.C. Doerr, Ind. Eng. Chem. Process Des. Dev. 4 (1965) 188.

    Google Scholar 

  4. R.L. Klimisch and G.J. Barnes, Environ. Sci. Technol. 6 (1972) 543.

    Google Scholar 

  5. V.I. Parvulescu, P. Grange and B. Delmon, Catal. Today 46 (1998) 233.

    Google Scholar 

  6. T.J. Pinnavaia, M.S. Tzou and S.D. Landau, J. Am. Chem. Soc. 107 (1985) 4783.

    Google Scholar 

  7. N.D. Skoularikis, R.W. Caughlin, A. Kostapapas, K.A. Carrado and S.L. Suib, Appl. Catal. 39 (1988) 61.

    Google Scholar 

  8. B.M. Choudary, A.D. Prasa, V. Bhuma and V. Swapna, J. Org. Chem. 57 (1992) 5841.

    Google Scholar 

  9. J.M. Adams, App. Clay Sci. 2 (1987) 309.

    Google Scholar 

  10. J.P. Cheng, M.C. Hausladen and R.T. Yang, J. Catal. 151 (1995) 135.

    Google Scholar 

  11. L.S. Cheng, R.T. Yang and N. Chen. J. Catal. 164 (1996) 70.

    Google Scholar 

  12. R.Q. Long and R.T. Yang, Appl. Catal. B 24 (2000) 13.

    Google Scholar 

  13. R.T. Yang, N. Tharappiwattananon and R.Q. Long, Appl. Catal. B 19 (1998) 289.

    Google Scholar 

  14. S.J. MacLachlan and D.M. Bibby, J. Chem. Soc., Dalton Trans. (1989) 895.

  15. D.J. Jones, J. Roziere, P. Maireles-Torres, A. Jimenez-Lopez, P. Olivera-Pastor, E. Rodriguez-Castellon and A.A.G. Tomlinson, Inorg. Chem. 34 (1995) 4611.

    Google Scholar 

  16. W. Hou, Q. Yan and X. Fu, J. Chem. Soc., Chem. Commun. (1994) 1371.

  17. C. Guo, W. Hou, M. Guo, Q. Yan and Y. Chen, Chem. Commun. (1997) 801.

  18. Y. Chen, W. Hou, C. Guo, Q. Yan and Y. Chen, J. Chem. Soc., Dalton Trans. (1997) 359.

  19. K. Tanabe, M. Misono, Y. Ono and H. Hattori, in: New Solid Acids and Bases (Kodansha, Tokyo, 1989) p. 60.

    Google Scholar 

  20. R. Nedjar, M.M. Borel and B. Raveau, Mat. Res. Bull. 20 (1986) 1291.

    Google Scholar 

  21. K.S.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Roupuerol and T. Diemieniewska, Pure & Appl. Chem. 57 (1985) 603.

    Google Scholar 

  22. X. Wang, W. Hou, X. Wang and Q. Yan, Appl. Catal. B 35 (2002) 185.

    Google Scholar 

  23. G. Busca, J. Mol. Catal. 43 (1987) 225.

    Google Scholar 

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Wang, X., Hou, W., Wang, H. et al. A Novel Catalyst for NO Reduction by CO. Catalysis Letters 82, 227–231 (2002). https://doi.org/10.1023/A:1020527214182

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