Abstract
A silica-pillared layered niobate (Si-Nb3O8) has been prepared by intercalating layered niobate with NH2(CH2)3Si(OEt)3. The results of XRD and BET measurement showed that the obtained product was a porous material with a high specific surface area and high thermal stability, and its layered structure remained unchanged after treatment with 5 vol% water vapor at 500 °C for 3 h. Using Si-Nb3O8 as support, a 2 wt% Cu/Si-Nb3O8 catalyst was prepared by impregnation of Cu(NO3)2 solution and the catalytic reduction of NO by CO was examined. The results showed that the catalyst had a good activity and selectivity, and the pretreatment of 5 vol% water vapor could obviously improve the conversion of NO reduction, while the selectivity of NO to N2 almost kept unchanged.
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References
J.F. Roth and R.C. Doerr, Ind. Eng. Chem. 53 (1961) 293.
R.A. Baker and R.C. Doer, J. Air Pollut. Control Assoc. 14 (1964) 409.
R.A. Baker and R.C. Doerr, Ind. Eng. Chem. Process Des. Dev. 4 (1965) 188.
R.L. Klimisch and G.J. Barnes, Environ. Sci. Technol. 6 (1972) 543.
V.I. Parvulescu, P. Grange and B. Delmon, Catal. Today 46 (1998) 233.
T.J. Pinnavaia, M.S. Tzou and S.D. Landau, J. Am. Chem. Soc. 107 (1985) 4783.
N.D. Skoularikis, R.W. Caughlin, A. Kostapapas, K.A. Carrado and S.L. Suib, Appl. Catal. 39 (1988) 61.
B.M. Choudary, A.D. Prasa, V. Bhuma and V. Swapna, J. Org. Chem. 57 (1992) 5841.
J.M. Adams, App. Clay Sci. 2 (1987) 309.
J.P. Cheng, M.C. Hausladen and R.T. Yang, J. Catal. 151 (1995) 135.
L.S. Cheng, R.T. Yang and N. Chen. J. Catal. 164 (1996) 70.
R.Q. Long and R.T. Yang, Appl. Catal. B 24 (2000) 13.
R.T. Yang, N. Tharappiwattananon and R.Q. Long, Appl. Catal. B 19 (1998) 289.
S.J. MacLachlan and D.M. Bibby, J. Chem. Soc., Dalton Trans. (1989) 895.
D.J. Jones, J. Roziere, P. Maireles-Torres, A. Jimenez-Lopez, P. Olivera-Pastor, E. Rodriguez-Castellon and A.A.G. Tomlinson, Inorg. Chem. 34 (1995) 4611.
W. Hou, Q. Yan and X. Fu, J. Chem. Soc., Chem. Commun. (1994) 1371.
C. Guo, W. Hou, M. Guo, Q. Yan and Y. Chen, Chem. Commun. (1997) 801.
Y. Chen, W. Hou, C. Guo, Q. Yan and Y. Chen, J. Chem. Soc., Dalton Trans. (1997) 359.
K. Tanabe, M. Misono, Y. Ono and H. Hattori, in: New Solid Acids and Bases (Kodansha, Tokyo, 1989) p. 60.
R. Nedjar, M.M. Borel and B. Raveau, Mat. Res. Bull. 20 (1986) 1291.
K.S.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Roupuerol and T. Diemieniewska, Pure & Appl. Chem. 57 (1985) 603.
X. Wang, W. Hou, X. Wang and Q. Yan, Appl. Catal. B 35 (2002) 185.
G. Busca, J. Mol. Catal. 43 (1987) 225.
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Wang, X., Hou, W., Wang, H. et al. A Novel Catalyst for NO Reduction by CO. Catalysis Letters 82, 227–231 (2002). https://doi.org/10.1023/A:1020527214182
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DOI: https://doi.org/10.1023/A:1020527214182