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In Situ Characterization of Catalysts Active in Partial Oxidations: TS-1 and Fe-MFI Case Studies

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Abstract

A concise review of the firmly established knowledge and of the unresolved problems concerning the structure and the reactivity of Ti and Fe sites in TS-1 and Fe-MFI partial oxidation catalysts is given. Some new experimental and theoretical results are also described.

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References

  1. M. Taramasso, G. Perego and B. Notari, US Patent. 4410501 (1983).

  2. G.M. Clerici, Appl. Catal. 68 (1991) 249.

    Google Scholar 

  3. G.M. Clerici, G. Bellussi, and U. Romano, J. Catal. 129 (1991) 159.

    Google Scholar 

  4. A. Zecchina, G. Spoto, S. Bordiga, F. Geobaldo, G. Petrini, G. Leofanti, M. Padovan, M. Mantegazza and P. Roffia, in: New Frontiers in Catalysis, eds. L. Guczi, F. Solymosi and P. Tétényi (Elsevier, Amsterdam, 1993) p. 719.

    Google Scholar 

  5. G. Bellussi, A. Carati, G.M. Clerici, G. Maddinelli and R. Millini, J. Catal. 133 (1992) 220.

    Google Scholar 

  6. W. Holderich, M. Messe and F. Naümann, Angew. Chem. Int. Ed. Engl. 27 (1988) 26.

    Google Scholar 

  7. B. Notari, Adv. Catal. 41 (1996) 253, and references therein.

    Google Scholar 

  8. P. Roffia, G. Leofanti, A. Cesana, M.A. Mantegazza, M. Padovan, G. Petrini, S. Tonti and P. Gervasutti, Stud. Surf. Sci. Catal. 55 (1990) 543.

    Google Scholar 

  9. M.A. Mantegazza, G. Leofanti, G. Petrini, M. Padovan, A. Zecchina and S. Bordiga, Stud. Surf. Sci. Catal. 82 (1994) 541.

    Google Scholar 

  10. M.A. Mantegazza, G. Petrini, G. Spanò, R. Bagatin and F. Rivetti, J. Mol. Catal. A 146 (1999) 223.

    Google Scholar 

  11. G. Tozzola, M.A. Mantegazza, G. Ranghino, G. Petrini, S. Bordiga, G. Ricchiardi, C. Lamberti, R. Zulian and A. Zecchina, J. Catal. 179 (1998) 64.

    Google Scholar 

  12. C. Zecchina, S. Bordiga, C. Lamberti, G. Ricchiardi, D. Scarano, G. Petrini, G. Leofanti and M. Mantegazza, Catal. Today 32 (1996) 97.

    Google Scholar 

  13. M.P. Coles, C.G. Lugmair, K.W. Terry and T.D. Tilly, Chem. Mater. 12 (2000) 122.

    Google Scholar 

  14. W. Adam, A. Corma, T. I. Reddy and M. Renz, J. Org. Chem. 62 (1997) 3631.

    Google Scholar 

  15. T. Blasco, M.A. Camblor, A. Corma, P. Esteve, J.M. Guil, A. Martínez, J.A. Perdigón-Melón and S. Valencia, J. Phys. Chem. B 102 (1998) 75.

    Google Scholar 

  16. R. Raja, G. Sankar and J. M. Thomas, J. Am. Chem. Soc. 123 (2001) 8153.

    Google Scholar 

  17. G. Sankar and J.M. Thomas, Acc. Chem. Res. 34 (2001) 571.

    Google Scholar 

  18. T. Katsuki and K.B. Sharpless, J. Am. Chem. Soc. 102 (1980) 5976.

    Google Scholar 

  19. P. Pitchen, E. Duñach, M.N. Deshmukh and H.B. Kagan, J. Am. Chem. Soc. 106 (1984) 8188.

    Google Scholar 

  20. Y. Gao, R.M. Hanson, J.M. Klunder, S.Y. Ko, H. Masamune and K.B. Sharpless, J. Am. Chem. Soc. 109 (1987) 5765.

    Google Scholar 

  21. S. Superchi and C. Rosini, Tetrahedron Asymm. 8 (1997) 349.

    Google Scholar 

  22. M. Bonchio, S. Calloni, F. Di Furia, G. Licini, G. Modena, S. Moro and W.A. Nugent, J. Am. Chem. Soc. 119 (1997) 6935.

    Google Scholar 

  23. M. Bonchio, G. Licini, G. Modena, O. Bortolini, S. Moro and W. A. Nugent, J. Am. Chem. Soc. 121 (1999) 6258.

    Google Scholar 

  24. R.L. Garten, W.N. Delgass and M. Boudart, J. Catal. 18 (1970) 90.

    Google Scholar 

  25. K.-I. Segawa, Y. Chen, J.E. Kubsh, W.N. Delgass, J.A. Dumesic and W.K. Hall, J. Catal. 76 (1982) 112.

    Google Scholar 

  26. J.W. Jermyn, T.J. Johnson, E.F. Vansant and J.H. Lunsford, J. Phys. Chem. 77 (1973) 2964.

    Google Scholar 

  27. D. Ballivet-Tkatchenko and G. Coudurier, Inorg. Chem. 18 (1979) 558.

    Google Scholar 

  28. T. Bein and P.A. Jacobs, J. Chem. Soc. Faraday Trans. 80 (1984) 1391.

    Google Scholar 

  29. J.B. Nagy, M. Van Eeno and E.G. Derouane, J. Catal. 58 (1979) 230.

    Google Scholar 

  30. G.I. Panov, V.I. Sobolev, K.A. Dubkov, V.N. Parmon, N.S. Ovanesyan, A.E. Shilov and A.A. Shteinman, React. Kin. Catal. Lett. 61 (1997) 251.

    Google Scholar 

  31. K.A. Dubkov, V.I. Sobolev, E.P. Talsi, M.A. Rodkin, N.H. Watkins, A.A. Shteinman and G.I. Panov, J. Mol. Catal. A 123 (1997) 155.

    Google Scholar 

  32. A. Stassinopoulos, G. Schulte, G.C. Papaefthymiou and J.P. Caradonna, J. Am. Chem. Soc. 113 (1991) 8686.

    Google Scholar 

  33. H.C. Tung, C. Kang and D.T. Sawyer, J. Am. Chem. Soc. 114 (1992) 3445.

    Google Scholar 

  34. S. Ménage, E.C. Wilkinson, L. Que, Jr., and M. Fontecave, Angew. Chem. Int. Ed. Engl. 34 (1995) 203.

    Google Scholar 

  35. J. Kim, E. Larka, E.C. Wilkinson and L. Que, Jr., Angew. Chem. Int. Ed. Engl. 34 (1995) 2048.

    Google Scholar 

  36. S. Ménage, J.B. Galey, J. Dumats, G. Hussler, M. Seité, I. Gautier Luneau, G. Chottard and M. Fontecave, J. Am. Chem. Soc. 120 (1998) 13370.

    Google Scholar 

  37. H. Zheng, S.J. Yoo, E. Münck and L. Que, Jr., J. Am. Chem. Soc. 122 (2000) 3789.

    Google Scholar 

  38. A.K. Uriarte, M.A. Rodkin, M.J. Gross, A.S. Kharitonov and G.I. Panov, Stud. Surf. Sci. Catal. 110 (1997) 857.

    Google Scholar 

  39. J. Green and H. Dalton, Biochem. J. 259 (1989) 167.

    Google Scholar 

  40. L. Shu, J.C. Neisheim, K. Kauffmann, E. Münck, J.D. Lipscomband L. Que, Jr., Science 275 (1997) 515.

    Google Scholar 

  41. P. Ratnasamy and R. Kumar, Catal. Today 9 (1991) 329.

    Google Scholar 

  42. E. Selli, A. Isernia and L. Forni, Phys. Chem. Chem. Phys. 2 (2000) 3301.

    Google Scholar 

  43. R. Leanza, I. Rossetti, I. Mazzola and L. Forni, Appl. Catal. A 205 (2001) 9.

    Google Scholar 

  44. S. Humbel, S. Sieber and K. Morokuma, J. Chem. Phys. 105 (1996) 1959.

    Google Scholar 

  45. S. Bordiga, P. Ugliengo, A. Damin, C. Lamberti, G. Spoto, A. Zecchina, G. Spanò, R. Buzzoni, L. Dalloro and F. Rivetti, Top. Catal. 15 (2001) 43.

    Google Scholar 

  46. P.J. Hay and W.R. Wadt, J. Chem. Phys. 82 (1985) 299.

    Google Scholar 

  47. A. Schaefer, C. Huber and R. Ahlrichs, J. Chem. Phys. 100 (1994) 5829.

    Google Scholar 

  48. R. Millini, E. Previdi Massara, G. Perego and G. Bellussi, J. Catal. 137 (1992) 497.

    Google Scholar 

  49. G. Perego, G. Bellussi, C. Corno, M. Taramasso, F. Buonuomo and A. Esposito, Stud. Surf. Sci. Catal. 28 (1987) 129.

    Google Scholar 

  50. C. Lamberti, S. Bordiga, A. Zecchina, G. Artioli, G. L. Marra and G. Spanò, J. Am. Chem. Soc. 123 (2001) 2204.

    Google Scholar 

  51. G. Ricchiardi, A. Damin, S. Bordiga, C. Lamberti, G. Spanò, F. Rivetti and A. Zecchina, J. Am. Chem. Soc. 123 (2001) 11409.

    Google Scholar 

  52. C. Lamberti, S. Bordiga, A. Zecchina, A. Carati, A.N. Fitch, G. Artioli, G. Petrini, M. Salvalaggio and G.L. Marra, J. Catal. 183 (1999) 222.

    Google Scholar 

  53. G. L. Marra, G. Artioli, A.N. Fitch, M. Milanesio and C. Lamberti, Microporous Mesoporous Mater. 40 (2000) 85.

    Google Scholar 

  54. C.A. Hijar, R.M. Jacubinas, J. Eckert, N.J. Henson, PJ. Hay and K.C. Ott, J. Phys. Chem. B 104 (2000) 12157.

    Google Scholar 

  55. P.F. Henry, M.T. Weller and C.C. Wilson, J. Phys. Chem. B 105 (2001) 7452.

    Google Scholar 

  56. M.R. Boccuti, K.M. Rao, A. Zecchina, G. Leofanti and G. Petrini, Stud. Surf. Sci. Catal. 48 (1989) 133.

    Google Scholar 

  57. A. Zecchina, G. Spoto, S. Bordiga, M. Padovan and G. Leofanti, Stud. Surf. Sci. Catal. 65 (1991) 671.

    Google Scholar 

  58. D. Scarano, A. Zecchina, S. Bordiga, F. Geobaldo, G. Spoto, G. Petrini, G. Leofanti, M. Padovan and G. Tozzola, J. Chem. Soc. Faraday Trans. 89 (1993) 4123.

    Google Scholar 

  59. A. Zecchina, G. Spoto, S. Bordiga, A. Ferrero, G. Petrini, M. Padovan and G. Leofanti, Stud. Surf. Sci. Catal. 69 (1991) 251.

    Google Scholar 

  60. G. Deo, A.M. Turek, I.E. Wachs, D.R.C. Huybrechts and P.A. Jacobs, Zeolites 13 (1993) 365.

    Google Scholar 

  61. C. Li, G. Xiong, Q. Xin, J. Liu, P. Ying, Z. Feng, J. Li, W. Yang, Y. Wang, G. Wang, X. Liu, M. Lin, X. Wang and E. Min, Angew. Chem. Int. Ed. 38 (1999) 2220.

    Google Scholar 

  62. T. Blasco, M. Camblor, A. Corma and J. Pérez-Parriente, J. Am. Chem. Soc. 115 (1993) 11806.

    Google Scholar 

  63. S. Bordiga, S. Coluccia, C. Lamberti, L. Marchese, A. Zecchina, F. Boscherini, F. Buffa, F. Genoni, G. Leofanti, G. Petrini and G. Vlaic, J. Phys. Chem. 98 (1994) 4125.

    Google Scholar 

  64. S. Pei, G.W. Zajac, J.A. Kaduk, J. Faber, B.I. Boyanov, D. Duck, D. Fazzini, T.I. Morrison and D.S. Yang, Catal. Lett. 21 (1993) 333.

    Google Scholar 

  65. S. Bordiga, F. Boscherini, S. Coluccia, F. Genoni, C. Lamberti, G. Leofanti, L. Marchese, G. Petrini, G. Vlaic and A. Zecchina, Catal. Lett. 26 (1994) 195.

    Google Scholar 

  66. L. Le Noc, D. Trong On, S. Solomykina, B. Echchahed, F. Béland, C. Cartier dit Moulin and L. Bonneviot, Stud. Surf. Sci. Catal. 101 (1996) 611.

    Google Scholar 

  67. S. Bordiga, F. Geobaldo, C. Lamberti, A. Zecchina, F. Boscherini, F. Genoni, G. Leofanti, G. Petrini, M. Padovan, S. Geremia and G. Vlaic, Nucl. Instr. Meth. B 97 (1995) 23.

    Google Scholar 

  68. C. Lamberti, S. Bordiga, D. Arduino, A. Zecchina, F. Geobaldo, G. Spanò, F. Genoni, G. Petrini, A. Carati, F. Villain and G. Vlaic, J. Phys. Chem. B 102 (1998) 6382.

    Google Scholar 

  69. D. Gleeson, G. Sankar, C.R.A. Catlow, J.M. Thomas, G. Spanó, S. Bordiga, A. Zecchina, and C. Lamberti, Phys. Chem. Chem. Phys. 2 (2000) 4812.

    Google Scholar 

  70. A. Thangaraj, R. Kumar, S.P. Mirajkar and B. Ratnasami, J. Catal. 130 (1991) 1.

    Google Scholar 

  71. A. Jentys and C.R.A. Catlow, Catal. Lett. 22 (1993) 251.

    Google Scholar 

  72. R. Millini, G. Perego and K. Seiti, Stud. Surf. Sci. Catal. 84 (1994) 2123.

    Google Scholar 

  73. A.J.M. de Mann and J. Sauer, J. Phys. Chem. 100 (1996) 5025.

    Google Scholar 

  74. P.E. Sinclair, G. Sankar, C.R.A. Catlow, J.M. Thomas and T. Maschmeyer, J. Phys. Chem. B 101 (1997) 4237.

    Google Scholar 

  75. P.E. Sinclair and C.R.A. Catlow, J. Phys. Chem. B 103 (1999) 1084.

    Google Scholar 

  76. C.M. Zicovich-Wilson, R. Dovesi and A. Corma, J. Phys. Chem. B 103 (1999) 988.

    Google Scholar 

  77. G. Ricchiardi, A. de Man and J. Sauer, Phys. Chem. Chem. Phys. 2 (2000) 2195.

    Google Scholar 

  78. F. Geobaldo, S. Bordiga, A. Zecchina, E. Giamello, G. Leofanti and G. Petrini, Catal. Lett. 16 (1992) 109.

    Google Scholar 

  79. V. Bolis, S. Bordiga, C. Lamberti, A. Zecchina, A. Carati, G. Petrini, F. Rivetti and G. Spanò, Microporous Mesoporous Mater. 30 (1999) 67.

    Google Scholar 

  80. V. Bolis, S. Bordiga, C. Lamberti, A. Zecchina, A. Carati, F. Rivetti, G. Spanò and G. Petrini, Langmuir 15 (1999) 5753.

    Google Scholar 

  81. H. Munakata, Y. Oumi and A. Miyamoto, J. Phys. Chem. B 105 (2001) 3493.

    Google Scholar 

  82. G.N. Vayssilov and R.A. van Santenn, J. Catal. 175 (1998) 170.

    Google Scholar 

  83. X. Feng and W. K. Hall, J. Catal. 166 (1997) 368.

    Google Scholar 

  84. W.K. Hall, X. Feng, J. Dumesic and R. Watwe, Catal. Lett. 52 (1998) 173.

    Google Scholar 

  85. A.M. Vodolin, V.I. Sobolev, and G.M. Zhidomirov, Kin. Catal. 39 (1998) 775.

    Google Scholar 

  86. A. Dubkov, N.S. Ovanesyan, A.A. Shteinman, K.A. Dubkov, V.I. Sobolev and G.I. Panov, Kin. Catal. 39 (1998) 792.

    Google Scholar 

  87. H.-Y. Chen and W.M.H. Sachtler, Catal. Today 42 (1998) 73.

    Google Scholar 

  88. R. Joyner and M. Stockenhuber, J. Phys. Chem. B 103 (1999) 5963.

    Google Scholar 

  89. M. Kögel, R. Mönning, W. Schwieger, A. Tissler and T. Turek, J. Catal. 182 (1999) 470.

    Google Scholar 

  90. P. Marturano, A. Kogelbauer and P. Prins, J. Catal. 190 (2000) 460.

    Google Scholar 

  91. P. Marturano, L. Drozdová, A. Kogelbauer and R. Prins, J. Catal. 192 (2000) 236.

    Google Scholar 

  92. H.-Y. Chen, El-M. El-Malki, X. Wang, R.A. van Santen and W.M.H. Sachtler, J. Mol. Catal. A 162 (2000) 159.

    Google Scholar 

  93. S. Bordiga, R. Buzzoni, F. Geobaldo, C. Lamberti, E. Giamello, A. Zecchina, G. Leofanti, G. Petrini, G. Tozzola and G. Vlaic, J. Catal. 158 (1996) 486.

    Google Scholar 

  94. A. Zecchina, F. Geobaldo, C. Lamberti, S. Bordiga, G. Turnes Palomino and C. Otero Areán, Catal. Lett. 42 (1996) 25.

    Google Scholar 

  95. A. Meagher, V. Nair and R. Szostak, Zeolites 8 (1988) 3.

    Google Scholar 

  96. K. Yogo, S. Tanaka, T. Ono, T. Mikami and E. Kikuchi, Micro. Mater. 3 (1994) 39.

    Google Scholar 

  97. P. Feies, J.B. Nagy, J. Halász and A. Oszkó, Appl. Catal. 61 (1990) 85.

    Google Scholar 

  98. A. Ribera, I.W.C.E. Arends, S. de Vries, J. Pérez-Ramí rez and R.A. Sheldon, J. Catal. 195 (2000) 287.

    Google Scholar 

  99. V.L. Zholobenko, I.N. Senchenya, L.M. Kustov and V.B. Kazanskii, Kinet. Katal. 32 (1991) 132.

    Google Scholar 

  100. V.I. Sobolev, G.I. Panov, A.S. Kharitonov, V.N. Romannikov, A.M. Volodin and K.G. Ione, J. Catal. 139 (1993) 435.

    Google Scholar 

  101. C. Lamberti, G. Turnes Palomino, S. Bordiga, D. Arduino, A. Zecchina and G. Vlaic, Jpn. J. Appl. Phys. 38 (1999) 55.

    Google Scholar 

  102. S.A. Axon, K.K. Fox, S.W. Carr and J. Klinowski, Chem. Phys. Lett. 189 (1992) 1.

    Google Scholar 

  103. D.W. Lewis, R.A. Catlow, J. Sankar and S.W. Carr, J. Phys. Chem. 99 (1995) 2377.

    Google Scholar 

  104. G. Spoto, A. Zecchina, G. Berlier, S. Bordiga, M.G. Clerici and L. Basini, J. Mol. Catal. A 158 (2000) 107.

    Google Scholar 

  105. L. Brabec, M. Jeschke, R. Klik, J. Nováková, L. Kubelková and J. Meusinger, Appl. Catal. A 170 (1998) 105.

    Google Scholar 

  106. E. Suzuki, K. Nakashiro and Y. Ono, Chem. Lett. (1998) 953.

  107. P.P. Notté, Topics in Catal. 13 (2000) 387.

    Google Scholar 

  108. C. Lamberti, S. Bordiga, A. Zecchina, M. Salvalaggio, F. Geobaldo and C. Otero Areán, J. Chem. Soc. Faraday Trans. 94 (1998) 1519.

    Google Scholar 

  109. C. Lamberti, G. Turnes Palomino, S. Bordiga, A. Zecchina, G. Spanò and C. Otero Areán, Catal. Lett. 63 (1999) 213.

    Google Scholar 

  110. G. Berlier, G. Spoto, S. Bordiga, G. Ricchiardi, P. Fisicaro, A. Zecchina, I. Rossetti, E. Selli, L. Forni, E. Giamello and C. Lamberti, J. Catal. (submitted).

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Zecchina, A., Bordiga, S., Spoto, G. et al. In Situ Characterization of Catalysts Active in Partial Oxidations: TS-1 and Fe-MFI Case Studies. Topics in Catalysis 21, 67–78 (2002). https://doi.org/10.1023/A:1020504115146

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