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Thermodynamic Description of Excess Isotherms in High-Pressure Adsorption of Methane, Argon and Nitrogen

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Abstract

In the present work the supercritical fluids argon, methane and nitrogen were picked out as examples, and the results of analysis concerning the adsorption of these fluids at activated carbon Norit R1 (Norit company, Germany) and SCS-3 (ISPE, Kiev) at different temperatures up to a pressure of 50 MPa are presented and discussed in this paper. The principle of working of the measuring device is described in this context as well.

A three-parameter isothermal equation is used to represent the adsorption equilibrium. The isothermal equation is based on a physical model concept which has already been used for the modelling of adsorption processes with a pressure up to 15 MPa.

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References

  • Harting, P., J. Germanus, and S. Beutekamp, Fortschrittberichte VDI, Reihe 3 Verfahrenstechnik, 554, 147-161.

  • Malbrunot, P., D. Vidal, J. Vermesse, R. Chahine, and T.K. Bose, “Adsorption Measurements of Argon, Neon, Krypton, Nitrogen and Methane on Activated Carbon up to 650 MPa,” Langmuir, 8, 577-580 (1992).

    Google Scholar 

  • Malbrunot, P., D.Vidal, J. Vermesse, R. Chahine, and T.K. Bose, “Adsorbent Helium Density Measurement and Its Effect on Adsorption Isotherms at High Pressure,” Langmuir, 13, 539-544 (1997).

    Google Scholar 

  • Neimark, A.V. and P.I. Ravikovich, “Calibration of Pore Volume in Adsorption Experiments and Theoretical Models,” Langmuir, 13, 5148-5160 (1997).

    Google Scholar 

  • Platzer, B. and G. Maurer, “Application of a Generalized Bender Equation of State to the Description of Vapour-Liquid Equilibria in Binary Systems,” Fluid Phase Equlibria, 84, 79-110 (1993).

    Google Scholar 

  • Salem, M., “Thermodynamik der Hochdruckadsorption einfacher Gase an porösen Adsorbenzien,” Dissertation, University of Leipzig, 1997.

  • Sievers, U. and S. Schulz, VDI-Forschungsheft, 609, 45-52 (1981).

    Google Scholar 

  • Sircar, S., “On the Measurements of Gibbsian Surface Excess,” Air Products and Chemicals, Inc. (1999).

  • Staudt, R., S. Bohn, F. Dreisbach, and J.U. Keller, “Gravimetric and Volumetric Measurements of Helium Adsorption Equilibria on Different Porous Solids,” Characterisation of Porous Solids, IV, 261-266.

  • Staudt, R., G. Saller, M. Tomalla, and J.U. Keller, “A Note on Gravimetric Measurements of Gas-Adsorption Equilibria,” Ber. Bunsenges. Phys. Chem. Bd., 97(1), 98-105 (1993).

    Google Scholar 

  • Talu, O., “Needs, Status, Techniques and Problems with Binary Gas Adsorption Experiments,” Adv. Colloid Interface Sci., 76/77, 227-269 (1998).

    Google Scholar 

  • Vazquez, I., M.P. Russell, D.R. Smith, and R. Radebaugh, “Helium Adsorption on Activated Carbons at Temperatures Between 4 and 76 K,” Advances in Cryogenic Engineering, 33, 1013-1021 (1987).

    Google Scholar 

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Herbst, A., Harting, P. Thermodynamic Description of Excess Isotherms in High-Pressure Adsorption of Methane, Argon and Nitrogen. Adsorption 8, 111–123 (2002). https://doi.org/10.1023/A:1020474217002

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  • DOI: https://doi.org/10.1023/A:1020474217002

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