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Gas-phase reaction of phenyl cation with diethylamine

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Abstract

Reactions of phenyl cations generated by the beta-decay of tritium in tritiated benzene were studied by a radiochemical method. Identified labeled products are ethylphenylamine (72%), diethylamine (15%) and diethylphenylamine (13%). A reaction mechanism is proposed and the relative yields of products are rationalized taking into account the energy estimates of plausible products by the B3LYP method.

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References

  1. I. S. IGNATYEV, T. A. KOCHINA, V. D. NEFEDOV, E. N. SINOTOVA, E. O. KALININ, Zh. Obsch. Khim., 65 (1995) 297.

    Google Scholar 

  2. I. S. IGNATYEV, T. A. KOCHINA, V. D. NEFEDOV, E. N. SINOTOVA, D. V. VRAZHNOV, Zh. Obsch. Khim., 65 (1995)304.

    Google Scholar 

  3. D. V. VRAZHNOV, I. S. IGNATYEV, E. O. KALININ, T. A. KOCHINA, V. D. NEFEDOV, E. N. SINOTOVA, Zh. Obsch. Khim., 67 (1997) 448.

    Google Scholar 

  4. T. A. KOCHINA, I. S. IGNATYEV, E. N. SINOTOVA, V. D. NEFEDOV, D. V. VRAZHNOV, E. O. KALININ, Zh. Org. Khim., 34 (1998) 1640.

    Google Scholar 

  5. T. A. KOCHINA, D. V. VRAZHNOV, I. S. IGNATYEV, J. Organomet. Chem., 549 (1997) 45.

    Google Scholar 

  6. M. MEOT-NER, J. Am. Chem. Soc., 101 (1979) 2383.

    Google Scholar 

  7. C. R. MOYLON, J. I. BRAUMAN, J. Am. Chem. Soc., 107 (1985) 761.

    Google Scholar 

  8. M. MEOT-NER, M. M. ROSS, J. E. COMPANA, J. Am. Chem. Soc., 107 (1985) 4839.

    Google Scholar 

  9. D. AUSLOOS, S. G. LIAS, J. Am. Chem. Soc., 108 (1986) 1792.

    Google Scholar 

  10. E. W. REDMAN, T. H. MORTON, J. Am. Chem. Soc., 108 (1986) 5701.

    Google Scholar 

  11. T. H. MORTON, Tetrahedron, 38 (1982) 3195.

    Google Scholar 

  12. H. E. AUDIER, T. H. MORTON, Org. Mass Spectrom., 28 (1993) 1218.

    Google Scholar 

  13. T. H. MORTON, Org. Mass Spectrom., 27 (1992) 353.

    Google Scholar 

  14. I. A. RANASINGHE, C. J. GLISH, Am. Soc. Mass Spectrom., 17 (1996) 473.

    Google Scholar 

  15. V. D. NEFEDOV, E. N. SINOTOVA, M. V. KORSAKOV, E. G. ALEKSEEV, Radiokhimiya, 15 (1976) 635.

    Google Scholar 

  16. V. D. NEFEDOV, N. P. KHARITONOV, E. N. SINOTOVA, T. A. KOCHINA, I. M. BALAKIN, Zh. Obsch. Khim., 50 (1980) 2499.

    Google Scholar 

  17. T. A. KOCHINA, D. V. VRAZHNOV, I. S. IGNATYEV, J. Organomet. Chem., 586 (1999) 241.

    Google Scholar 

  18. M. SPERANZA, M. D. SEFCIK, J. M. S. HENIS, P. P. GASPAR, J. Am. Chem. Soc., 99 (1977) 5583.

    Google Scholar 

  19. I. S. IGNATYEV, T. SUNDIUS, J. Phys. Chem., A105 (2001) 4535.

    Google Scholar 

  20. M. SPERANZA, Chem. Rev., 93 (1993) 2933.

    Google Scholar 

  21. A. D. BECKE, J. Chem. Phys., 98 (1993) 5648.

    Google Scholar 

  22. C. LEE, W. YANG, R. G. PARR, Phys. Rev., B37 (1988) 785.

    Google Scholar 

  23. M. J. FRISCH, G. W. TRUCKS, H. B. SCHLEGEL, P. M. W. GILL, B. G. JONSON, M. A. ROBB, J. R. CHEESEMAN, T. KEITH, G. A. PETERSSON, J. A. MONTGOMERY, K. RAGHAVACHARI, M. A. AL-LAHAM, V. G. ZAKRZEWSKI, J. V. ORTIZ, J. B. FORESMAN, J. CIOSLOWSKI, B. B. STEFANOV, A. NANAYAKKARA, M. CHALLACOMBE, C. Y. PENG, P. Y. AYALA, W. CHEN, M. W. WONG, J. L. ANDRES, E. S. REPLOGLE, R. GOMPERTS, R. L. MARTIN, D. J. FOX, J. S. BINKLEY, D. J. DEFREES, J. BAKER, J. P. STEWART, M. HEAD-GORDON, C. GONZALEZ, J. A. POPLE, Gaussian 94, Revision E.2. Gaussian, Inc., Pittsburgh PA, 1995.

    Google Scholar 

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Authors and Affiliations

  1. Institute for Silicate Chemistry, Russian Academy of Sciences, Odoevskogo 24, corp.2, 199155, St. Petersburg, Russia

    T. A. Kochina & D. V. Vrazhnov

  2. Radiochemistry Laboratory, Department of Chemistry, St. Petersburg State University, Universitetskiy pr. 2, 198904, St. Petersburg, Russia

    I. S. Ignatyev, E. O. Kalinin & E. N. Sinotova

Authors
  1. T. A. Kochina
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  2. D. V. Vrazhnov
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  3. I. S. Ignatyev
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  4. E. O. Kalinin
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  5. E. N. Sinotova
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Kochina, T.A., Vrazhnov, D.V., Ignatyev, I.S. et al. Gas-phase reaction of phenyl cation with diethylamine. Journal of Radioanalytical and Nuclear Chemistry 253, 435–437 (2002). https://doi.org/10.1023/A:1020473620675

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