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Thermodynamics of Lithium Intercalates in Carbonized Fabric

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Abstract

The method of quasi-equilibrium galvanostatic curves was applied to study the thermodynamics of lithium deintercalation from the system Li x C6 (solid phase)/Li+ (solution) in the interval 293-323 K and the thermodynamic characteristics (ΔG, ΔS, ΔH) of lithium intercalation compounds in a carbonized fabric in relation to the degree of intercalation x.

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REFERENCES

  1. Vetter, K.J., Elektrochemische Kinetik, Berlin: Springer, 1961.

    Google Scholar 

  2. Daniels, F. and Alberty, R.A., Physical Chemistry, New York: Wiley, 1975, 4th ed.

    Google Scholar 

  3. Shutaikina, S.M., Ol'shanskaya, L.N., Evpalov, D.A., and Popova, S.S., Abstracts of Papers, Sovremennye problemy teoreticheskoi i eksperimental'noi khimii: Vserossiiskaya konferentsiya molodykh uchenykh (Modern Problems of Theoretical and Experimental Chemistry: Russian Conf. of Young Scientists), Saratov: Saratov. Gos. Univ., June 25-26, 1997, pp. 258-259.

    Google Scholar 

  4. Gavrilyuk, V.I. and Plakhotnik, V.N., Zh. Fiz. Khim., 1994, vol. 68, no. 8, pp. 1373-1376.

    Google Scholar 

  5. Dai, Y., Wang, Y., Eshkerari, Y., et al., J. Electrochem. Soc., 1998, vol. 145, no. 4, pp. 1179-1183.

    Google Scholar 

  6. Atsashi, F., Minori, Y., Zempachi, O., et al., J. Electrochem. Soc., 1998, vol. 145, no. 1, pp. 172-178.

    Google Scholar 

  7. Billand, D., Herry, F.X., and Willman, P., J. Power Sources: 18th. Int. Power Sources Symp. (Stratfordupon-Avon, April 1993), p. 374.

  8. Zhend, T., Xue, J.S., and Dohn, J.R., Chem. Mater., 1996, vol. 8, no. 2, pp. 389-393.

    Google Scholar 

  9. Kabanov, B.N., Chekavtsev, A.V., Petukhova, P.I., et al., Elektrokhimiya, 1986, vol. 22, no. 3, pp. 415-417.

    Google Scholar 

  10. Pominova, T.V., Popova, S.S., and Ol'shanskaya, L.N., Elektrokhimiya, 2000, vol. 36, no. 4, pp. 448-454.

    Google Scholar 

  11. Volgin, M.A., Churikov, A.V., Konoplyantseva, N.A., et al., Elektrokhimiya, 1998, vol. 34, no. 7, pp. 761-768.

    Google Scholar 

  12. Danil'chuk, T.N., Petrova, G.N., Efimov, O.N., et al., Elektrokhimiya, 1998, vol. 34, no. 7, pp. 770-777.

    Google Scholar 

  13. Imanishi, N., Kumai, K., Kokugam, H., et al., Solid State Ionics, 1998, vol. 107, nos. 1-2, pp. 135-144.

    Google Scholar 

  14. Levi, M.D. and Aurbach, P., J. Electroanal. Chem., 1997, vol. 421, nos. 1-2, pp. 79-88.

    Google Scholar 

  15. Skundin, A.M. and Egorkina, O.Yu., Elektrokhimiya, 1997, vol. 33, no. 4, pp. 464-468.

    Google Scholar 

  16. Volgin, M.A., Churikov, A.V., and L'vov, A.L., Elektrokhimiya, 1999, vol. 35, no. 12, pp. 1462-1468.

    Google Scholar 

  17. Imanishi, N., Kashiwagi, H., Ishikawa, T., et al., J. Electrochem. Soc., 1993, vol. 140, no. 2, pp. 315-320.

    Google Scholar 

  18. Volgin, M.A., Kulikov, L.N., Konoplyantseva, N.A., et al., Elektrokhim. Energet., 2001, vol. 1, nos. 1-2, pp. 50-55.

    Google Scholar 

  19. Piao, T., Park, S.M., and Dobital, C.-H., J. Electrochem. Soc., 1999, vol. 146, no. 8, pp. 2794-2798.

    Google Scholar 

  20. Fialkov, A.S., Uglerod, mezhsloevye soedineniya i kompozity na ego osnove (Carbon and Intercalation Compounds and Composites on Its Base), Moscow: Aspekt, 1997.

    Google Scholar 

  21. Skundin, A.M. and Egorkina, O.Yu., Elektrokhimiya, 1995, vol. 31, no. 4, pp. 373-375.

    Google Scholar 

  22. Ubbelohde, A.R. and Lewis, F.A., Graphite and Its Crystal Compounds, Oxford: Clarendon, 1960.

    Google Scholar 

  23. Spravochnik po kompozitsionnym materialam (Reference Book of Composites), Lyubin, D.Zh., Ed., Moscow: Mashinostroenie, 1988, vol. 1.

    Google Scholar 

  24. Butler J.N., Adv. Electrochem. Electrochem. Eng., 1970, vol. 7, pp. 77-175.

    Google Scholar 

  25. Sautin, S.N., Planirovanie eksperimenta v khimii i khimicheskoi tekhnologii (Design of Experiments in Chemistry and Chemical Technology), Leningrad: Khimiya, 1975.

    Google Scholar 

  26. Zakgeim, A.Yu., Vvedenie v modelirovanie khimikotekhnologicheskikh protsessov (Introduction to Simulation of Processes of Chemical Technology), Moscow: Khimiya, 1973.

    Google Scholar 

  27. Gordon, A.J. and Ford, R.A., The Chemist's Companion. A Handbook of Practical Data, Techniques and References, New York: Wiley-Interscience, 1972.

    Google Scholar 

  28. Takami, N., Saton, A., Ohsaki, T., et al., Electrochim. Acta, 1997, vol. 42, no. 6, pp. 2437-2543.

    Google Scholar 

  29. Rabinovich, V.A. and Khavin, Z.Ya., Kratkii khimicheskii spravochnik (Concise Chemical Reference Book), Leningrad: Khimiya, 1978.

    Google Scholar 

  30. Terina, E.M. and Ol'shanskaya, L.N., Aktual'nye problemy elektrokhimicheskoi tekhnologii: Sbornik trudov molodykh uchenykh. Engel's, mai 2000 g. (Topical Problems of Electrochemical Technology: Coll. of Sci. Works of Young Scientists, Engels, May 2000), Saratov: Saratov. Gos, Tekh. Univ., 2000, pp. 19-22.

    Google Scholar 

  31. Sanches, L., Farcy, J., and Pereira-Ramos, J.P., Electrochim. Acta, 1998, vol. 43, no. 8, pp. 935-941.

    Google Scholar 

  32. Imanishi, N., Ohashi, S., Ichikawa, T., et al., J. Power Sources, 1992, vol. 39, no. 2, pp. 185.

    Google Scholar 

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  1. Technological Institute, Saratov State Technical University, Engels, Saratov oblast, Russia

    L. N. Ol'shanskaya & E. N. Astaf'eva

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  1. L. N. Ol'shanskaya
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  2. E. N. Astaf'eva
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Ol'shanskaya, L.N., Astaf'eva, E.N. Thermodynamics of Lithium Intercalates in Carbonized Fabric. Russian Journal of Applied Chemistry 75, 740–744 (2002). https://doi.org/10.1023/A:1020398126438

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