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Syntheses of [Rh(NH3)5Cl][MCl6] (M = Re, Os, Ir) and Investigation of Their Thermolysis Products. Crystal Structure of [Rh(NH3)5Cl][OsCl6]

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Abstract

Binary complex salts [Rh(NH3)5Cl][MCl6], where M = Re, Os, Ir, have been synthesized and characterized. X-ray diffraction analysis indicated that the salts are isostructural. According to X-ray phase analysis, the products of their thermolysis in hydrogen are monophase stoichiometric nonequilibrium solid solutions Rh0.5M0.5 (M = Re, Os, Ir). The molecular and crystal structures of [Rh(NH3)5Cl][OsCl6] were determined in an X-ray structural analysis.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk

    S. A. Gromilov, S. V. Korenev, I. A. Baidina, I. V. Korolkov & K. V. Yusenko

  2. Novosibirsk State University, Russia

    S. A. Gromilov, S. V. Korenev, I. A. Baidina, I. V. Korolkov & K. V. Yusenko

Authors
  1. S. A. Gromilov
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  2. S. V. Korenev
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  3. I. A. Baidina
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  4. I. V. Korolkov
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  5. K. V. Yusenko
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Gromilov, S.A., Korenev, S.V., Baidina, I.A. et al. Syntheses of [Rh(NH3)5Cl][MCl6] (M = Re, Os, Ir) and Investigation of Their Thermolysis Products. Crystal Structure of [Rh(NH3)5Cl][OsCl6]. Journal of Structural Chemistry 43, 488–494 (2002). https://doi.org/10.1023/A:1020349402311

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  • DOI: https://doi.org/10.1023/A:1020349402311

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