Abstract
Electrochemical behavior of nickel sulfide (NiS) in 0.5 M solutions of Na2SO4, CuSO4at pH 2.0-2.2 and T = 90°C was studied. A possibility was shown for depassivation and efficient dissolution of nickel sulfides upon addition of KBr to the electrolyte.
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REFERENCES
Chizhikov, D.M., Gulyanitskaya, Z.F., and Pliginskaya, L.V., Elektrometallurgiya medno-nikelevykh sul'fidnykh splavov v vodnykh rastvorakh (Electrometallurgy of Copper-Nickel Sulfide Alloys in Aqueous Solutions), Moscow: Nauka, 1977.
Sinel'nikov, N.V. and Makarov, S.N., Gidrometallurgiya medi i nikelya (Hydrometallurgy of Copper and Nickel), Moscow, 1976.
Ogorodnikov, Yu.I. and Ponomareva, E.I., Elektrovyshchelachivanie khal'kogenidnykh materialov (Electroleaching of Chalcogenide Materials), Alma-Ata: Nauka, 1983.
Borbat, V.F. and Leshch, I.Yu., Novye protsessy v metallurgii nikelya i kobal'ta (New Processes in Nickel and Cobalt Metallurgy), Moscow: Metallurgiya, 1976.
Gidrometallurgiya: Sbornik perevodov (Hydrometallurgy: Coll. of Translations), Laskorin, B.N., Ed., Moscow: Metallurgiya, 1978.
Muravchik, B.L. and Kipnis, A.Ya., Zh. Prikl. Khim., 1982, vol. 55, no. 12, pp. 2650-2654.
Ivanov, I.S., Zh. Prikl. Khim., 1968, vol. 41, no. 4, pp. 1017-1020.
Marczenko, Z., Kolorymetryczne oznaczanie pierwiastkow, Warsaw: Naukowa-Techniczne, 1968.
Sandell, E.B., Colorimetric Determination of Traces of Metals, New York: Interscience, 1959.
Sladkov, G.A. and Burygina, E.Kh., Zh. Prikl. Khim., 1988, vol. 51, no. 7, pp. 1489-1492.
Kheifets, V.L. and Gran', G.V., Elektroliz nikelya (Electrolysis of Nickel), Moscow: Metallurgiya, 1975.
Podchainova, V.N. and Simonova, L.N., Med' (Copper), Moscow: Nauka, 1990.
Charlot, G., Les methods de la chimie analytique. Analyse quantitative minerale, Paris: Masson, 1961, 4th ed.
Ksenzenko, V.I. and Stasinovich, D.S., Khimiya i tekhnologiya broma, ioda i ikh soedinenii (Chemistry and Technology of Bromine, Iodine, and Their Compounds) Moscow: Khimiya, 1979.
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Natorkhin, M.I. Effect of KBr Additions on NiS Anodic Dissolution in Sulfate Electrolytes. Russian Journal of Applied Chemistry 75, 849–851 (2002). https://doi.org/10.1023/A:1020343503665
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DOI: https://doi.org/10.1023/A:1020343503665