Abstract
Spectrophotometry, pH-metry, and kinetic method were applied to study the complexation and redox decomposition of cerium hydroxo complexes formed in the systems Ce4 +-SO4 2--H m L, where H m L (m = 2, 3, 4) are, respectively lactic, malic, and tartaric acids.
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REFERENCES
Kiselev, Yu.M., Zh. Neorg. Khim., 1999, vol. 44, no. 5, pp. 711-717.
Kiselev, Yu.M., Zh. Neorg. Khim., 1998, vol. 43, no. 5, pp. 759-767.
Koordinatsionnaya khimiya redkozemel'nykh elementov (Coordination Chemistry of Rare-Earth Elements), Spitsyn, V.I. and Martynenko, L.I., Eds., Moscow: Mos. Gos. Univ., 1974.
Kiselev, Yu.M., Vestn. Mos. Gos. Univ., 1998, vol. 38, no. 1, pp. 3-10.
Sarana, N.V., in Trudy Leningradskogo tekhnologicheskogo instituta tsellyulozno-bumazhnoi promyshlennosti (Coll. of Sci. Works of Leningrad Technol. Inst. of Pulp and Paper Industry), 1969, no. 24, pp. 56-59.
Dolgoplosk, B.A. and Tinyakova, E.I., Okislitel'novosstanovitel'nye sistemy kak istochnik svobodnykh radikalov (Redox Systems as a Source of Free Radicals), Moscow: Nauka, 1972.
Inczedi, J., Analytical Application of Complex Equilibria, Translation Editor J. Tyson, Budapest: Academia Kiado, Coll House: Ellis Horwood, 1976.
Duka, G.G., Batyr, D.G., Romanchuk, L.S., and Sychev, A.Ya., Koord. Khim., 1990, vol. 16, no. 1, pp. 93-106.
Rao, B.M., Sastrys, T.P., and Parekh, T., Z. phys. Chem., 1983, vol. 264, no. 5, pp. 906-920.
Krishna, B. and Tewari, K.C., J. Chem. Soc., 1961, no. 25, pp. 3097-3102.
Mehrotra, R.N. and Chosh, S., Z. phys. Chem. (DDR), 1965, vol. 230, no. 3/4, pp. 231-239.
Lahid, A. and Alexander, A., J. Chem. Soc. Dalton Trans., 1974, no. 23, pp. 2521-2530.
Luzan, A.A. and Yatsimirskii, K.B., Zh. Neorg. Khim., 1968, vol. 13, no. 12, pp. 3216-3221.
Vakhramova, G.P., Pechurova, N.I., and Spitsyn, V.I., Izv. Akad. Nauk SSSR, Ser. Khim., 1974, no. 10, pp. 2361-2366.
Vakhramova, G.P., Pechurova, N.I., and Spitsyn, V.I., Zh. Neorg. Khim., 1974, vol. 19, no. 10, pp. 2722-2725.
Kostromina, N.A., Kumok, V.N., and Skorik, N.A., Khimiya koordinatsionnykh soedinenii (Chemistry of Coordination Compounds), Moscow: Vysshaya Shkola, 1990.
Trubacheva, L.V. and Pechurova, N.I., Zh. Neorg. Khim., 1981, vol. 26, no. 12, pp. 3254-3258.
Skorik, N.A. and Artish, A.S., Zh. Neorg. Khim., 1985, vol. 30, no. 8, pp. 1994-1997.
Bachmann, K. and Lieser, K.H., Ber. Bunsgesell. Phys. Chem., 1963, vol. 67, no. 8, pp. 810-816.
Voskresenskaya, O.O. and Skorik, N.A., Zh. Neorg. Khim., 2000, vol. 45, no. 12, pp. 2090-2098.
Voskresenskaya, O.O. and Skorik, N.A., Zh. Neorg. Khim., 2000, vol. 45, no. 4, pp. 719-726.
Yatsimirskii, K.B., Kinetic Methods of Analysis, Oxford: Pergamon, 1966.
Kolthoff, I.M., Belcher, R, Stenger, V. A., and Matsuyama, G., Volumetric Analysis, vol. III, Titration Methods: Oxidation-Reduction Reactions, New York: Interscience, 1957.
Sillen, L.G. and Martell, A.E., Stability Constants of Metal-Ion Complexes: Special publication no. 17, London: Chemical Soc., 1964.
Dobrynina, N.A. and Martynenko, L.I., Problemy sovremennoi khimii koordinatsionnykh soedinenii (Problems of Modern Chemistry of Coordination Compounds), Burkov, K.A., Ed., Leningrad: Len. Gos. Univ., 1989, p. 98.
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Voskresenskaya, O.O., Skorik, N.A. Complexation and Intramolecular Redox Decomposition of Cerium(IV) Hydroxo Complexes with Oxycarboxylic Acids. Russian Journal of Applied Chemistry 75, 866–874 (2002). https://doi.org/10.1023/A:1020303822320
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DOI: https://doi.org/10.1023/A:1020303822320