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Simulation of the Kinetics of Cyclohexane Oxidation in a Barrier Discharge Reactor

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Abstract

The kinetics of cyclohexane oxidation in a barrier discharge reactor was simulated for a single voltage pulse. A significant difference between the yields of O3 obtained experimentally (not detected) and theoretically (15.5 wt %) suggests that O3 was absent from the reaction mixture because of a fast reaction between O(3 P) and an excited cyclohexane molecule. This hypothesis was indirectly supported by experimental data on the oxidation of a mixture of n-hexane and cyclohexene (50 : 50 wt %). The integrated rate constant of the reaction of O(3 P) with n-hexane was 1.4 × 10–12 cm3/s, which is an order of magnitude higher than the published value 1.2 × 10–13 cm3/s.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry, Siberian Division, Russian Academy of Sciences, Akademicheskii pr. 3, Tomsk, 634021, Russia

    G. S. Shchegoleva, A. Yu. Ryabov & E. E. Sirotkina

Authors
  1. S. V. Kudryashov
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  2. G. S. Shchegoleva
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  3. A. Yu. Ryabov
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  4. E. E. Sirotkina
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Kudryashov, S.V., Shchegoleva, G.S., Ryabov, A.Y. et al. Simulation of the Kinetics of Cyclohexane Oxidation in a Barrier Discharge Reactor. High Energy Chemistry 36, 349–354 (2002). https://doi.org/10.1023/A:1020254818916

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