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Dielectric Relaxation Study of Chloro Group with Associative Liquids. II. 1,2-Dichloroethane with Methanol, Ethanol, and 1-Propanol

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Abstract

Frequency spectra of the complex permittivity for 1,2-dichloroethane–alcohol binary mixtures have been determined over the frequency range 10 MHz to 20 GHz at 15, 25, 35, and 45°C, using the time-domain reflectometry (TDR) technique, for 11 compositions of each 1,2 dichloroethane–alcohol system. The alcohols used in the study were methanol, ethanol, and 1-propanol. The relaxation in these systems can be described by a single relaxation time using the Debye model. The static dielectric constant, relaxation time, the corresponding excess dielectric properties, Kirkwood correlation factor, and Bruggeman factor of the mixtures have been determined. The static dielectric constants for the mixtures have been fitted with the modified Bruggeman model.

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Authors and Affiliations

  1. Postgraduate Department of Applied Electronics, Maharashtra Udayagiri Mahavidyalaya, Udgir, 413 517, India

    V. P. Pawar

  2. Department of Electronics and Computer Science, Dr. B. A. M. University, Aurangabad, 431 004, India

    S. C. Mehrotra

Authors
  1. V. P. Pawar
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  2. S. C. Mehrotra
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Pawar, V.P., Mehrotra, S.C. Dielectric Relaxation Study of Chloro Group with Associative Liquids. II. 1,2-Dichloroethane with Methanol, Ethanol, and 1-Propanol. Journal of Solution Chemistry 31, 577–588 (2002). https://doi.org/10.1023/A:1020245713583

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  • DOI: https://doi.org/10.1023/A:1020245713583

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