Skip to main content
SpringerLink
Log in

Synthesis and crystal structure of an unsymmetric dysprosium(III) cryptate

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Synthesis, crystal and molecular structure of [Dy(H3L)(NO3)(H2O)](ClO4)2 ⋅ H2O are reported. The complex crystallizes in the orthorhombic system, space group Pbca with lattice parameters a = 16.8036(3) Å, b = 20.9756(3) Å, c = 25.1113(4) Å, and D calc = 1.797 Mg m−3 for Z = 8. The coordination number of dysprosium(III) is 9, and its coordination geometry is a distorted monocapped square antiprisms. In the cryptate, a water molecule acts as a guest molecule encapsulated in the cryptate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Alexander, V. Chem. Rev. 1995, 95, 273.

    Google Scholar 

  2. Lehn, J.-M. Angew. Chem. Int. Ed. Engl. 1990, 29, 1304.

    Google Scholar 

  3. Sabbatini, N.; Guardigi, M. Coord. Chem. Rev. 1993, 123, 201.

    Google Scholar 

  4. Choppin, G.R.; Peterman, D.R. Coord. Chem. Rev. 1998, 174, 283.

    Google Scholar 

  5. Ghosh, P.; Bharadwaj, P.K.; Ghosh, J., Roy., S. J. Am. Chem. Soc. 1997, 119, 11903.

    Google Scholar 

  6. Parker, D.; Williams, J.A.G.; J. Chem. Soc., Dalton Trans. 1996, 3613.

  7. Richardson, F. Chem. Rev. 1982, 82, 541.

    Google Scholar 

  8. Mathis, G. Clin. Chem. 1993, 39, 1993.

    Google Scholar 

  9. Feng, C.J.; Luo, Q.H.; Duan, C.Y.; Shen, M.C.; Liu, Y.J. J. Chem. Soc., Dalton Trans. 1998, 1377.

  10. Chen, Q.-Y.; Feng, C.J.; Luo, Q.H.; Duan, C.Y.; Yu, X.S.; De-Jun, L. Eur. J. Inorg. Chem. 2001, 1063.

  11. Avecilla, F.; Bastida, R.; Blas, A. de; Fenton, D.E.; Macias, A.; Rodriguez, A.; Rodriguez-Blas, T.; Garcia-Granda, S.; Corza-Suarez, R. J. Chem. Soc., Dalton Trans. 1997, 409.

  12. Kimura, E.; Young, S.; Collman, J.P. Inorg. Chem. 1970, 9, 118.

    Google Scholar 

  13. Taniguchi, S. Bull. Chem. Soc. Jpn. 1984, 57, 2683.

    Google Scholar 

  14. AINT Software Reference Manual; Siemens Energy & Automation Inc.: Madison, WI, 1996.

  15. Sheldrick G.M. SADABS Absortion Correction Program; University of Goeltingen: Germany, 1996.

    Google Scholar 

  16. SHELXTL, Version 5.0, Reference Manual; Siemens Energy & Automation Inc.: Madison, WI, 1997.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Huangshan College, Huangshan, 245021, People's Republic of China

    Qiu-Yun Chen

  2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, People's Republic of China

    Qin-Hui Luo

  3. X-ray Crystallography Unit, School of Physics, University Sains Malaysia, 11800 USM, Penang, Malaysia

    Hoong-kun Fun

Authors
  1. Qiu-Yun Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Qin-Hui Luo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hoong-kun Fun
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Qiu-Yun Chen.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chen, QY., Luo, QH. & Fun, Hk. Synthesis and crystal structure of an unsymmetric dysprosium(III) cryptate. Journal of Chemical Crystallography 32, 377–380 (2002). https://doi.org/10.1023/A:1020236920349

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1020236920349

Search

Navigation