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Crystal structure of bis(η5-methylcyclopentadienyl)-bis(4-methylbenzenesulfonato-O)-molybdenum(IV)

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Abstract

The compound bis(η5-methylcyclopentadienyl)-bis(4-methylbenzenesulfonato-O)-molybdenum (IV) crystallizes in space-group P21/c, a = 8.2956(5), b = 26.896(3), c = 11.4196(11) Å, β = 96.101(7)°, Z = 4. The sulfonate ligands are monodentate and the molybdenum atom has pseudotetrahedral coordination geometry, with angles O–Mo–O 72.0(1)° and Cp–Mo–Cp 134.9(1)° (Cp = ring centroid).

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Authors and Affiliations

  1. Department of Chemistry, University of Oregon, Eugene, Oregon, 97403

    Christoph Balzarek, David R. Tyler & Timothy J. R. Weakley

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  1. Christoph Balzarek
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  2. David R. Tyler
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  3. Timothy J. R. Weakley
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Correspondence to Timothy J. R. Weakley.

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Balzarek, C., Tyler, D.R. & Weakley, T.J.R. Crystal structure of bis(η5-methylcyclopentadienyl)-bis(4-methylbenzenesulfonato-O)-molybdenum(IV). Journal of Chemical Crystallography 32, 161–163 (2002). https://doi.org/10.1023/A:1020231717855

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  • DOI: https://doi.org/10.1023/A:1020231717855

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