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Crystal structure of the addition compound of [Ni(meso-cth)][Cr(ox)2(bpy)](H2O)(ClO4) with weak coordination bonds and hydrogen bonds

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Abstract

A new ionic complex [Ni(meso-cth)][Cr(ox)2(bpy)](H2O)(ClO4) [meso-cth = meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, ox = oxalato ainon, bpy = 2,2′-bipyridine] was prepared and its structure was determined. The complex was found to crystallized in monoclinic space group P2(1)/n, with a = 13.6000(4) Å, b = 18.763(5) Å, c = 14.995(4) Å, β =106.958(5)°, V = 3659.9(17) Å3, and Z = 4. The structure consisted of cationic [Ni(meso-cth)]2+, anionic [Cr(ox)2(bpy)]−, and perchlorate anions; the cationic [Ni(meso-cth)]2+ and anionic [Cr(ox)2(bpy)]− units were related by weak coordination bonds and hydrogen bonds.

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Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin, 300071, People's Republic of China

    Jin-Kui Tang, Shu-Feng Si, En-Qing Gao, Dai-Zheng Liao, Zong-Hui Jiang & Shi-Ping Yan

  2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, People's Republic of China

    Zong-Hui Jiang

  3. State Key Laboratory of Chemistry and Application of Rare Earth Materials, Peking University, Beijing, 100871, People's Republic of China

    Shi-Ping Yan

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  1. Jin-Kui Tang
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  2. Shu-Feng Si
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  3. En-Qing Gao
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  4. Dai-Zheng Liao
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  5. Zong-Hui Jiang
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  6. Shi-Ping Yan
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Correspondence to Dai-Zheng Liao.

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Tang, JK., Si, SF., Gao, EQ. et al. Crystal structure of the addition compound of [Ni(meso-cth)][Cr(ox)2(bpy)](H2O)(ClO4) with weak coordination bonds and hydrogen bonds. Journal of Chemical Crystallography 32, 331–335 (2002). https://doi.org/10.1023/A:1020213709871

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