Skip to main content
Log in

Visible light induced hydrogen production with Mg chlorophyll-a from spirulina and colloidal platinum

  • Published:
Biometals Aims and scope Submit manuscript

Abstract

Photoinduced hydrogen production with Mg chlorophyll-a from spirulina as a visible light photosensitizer by use of three component system consisting of nicotineamide adenine dinucleotide phosphate, reduced form (NADPH) as an electron donor, methylviologen as electron relay reagent and colloidal platinum as hydrogen evolution catalyst was investigated. By the addition of NADPH, the photostability of Mg chlorophyll-a was increased. The effective visible-light induced hydrogen production system with colloidal platinum was established using Mg chlorophyll-a.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Brugger PA, Cuendet P, Grätzel M. 1981 Ultrafine and specific catalysts affording efficient hydrogen evolution from water under visible light illumination. J Am Chem Soc 103, 2923-2927.

    Google Scholar 

  • Darwent JR, Douglas P, Harriman A, Porter G, Richoux MC. 1982 Metal phthalocyanines and porphyrins as photosensitizers for reduction of water to hydrogen. Coord Chem Rev 44, 93-126.

    Google Scholar 

  • Itoh T, Ishii A, Kodera Y, Matsushima A, Hiroto M, Nishimura H, Tsuzuki T, Kamachi T, Okura I. 1998 Photostable chlorophyll a with poly(vinylpyrrolidone)-smectite catalyzes photoreduction and hydrogen gas evolution by visible light. Bioconjug Chem 9, 409-412.

    Google Scholar 

  • Kiwi J, Grätzel M. 1979 Protection size factors, and reaction dynamics of colloidal redox catalysis mediating light induced hydrogen evolution from water. J Am Chem Soc 101, 7214-7217.

    Google Scholar 

  • Okura I. 1985 Hydrogenase and its application for photoinduced hydrogen evolution. Coord Chem Rev 68, 53-101.

    Google Scholar 

  • Okura I, Aono S, Yamada A. 1985 Photoinduced electron transfer between Zn(TPPS) 3?3 and viologens. J Phys Chem 89: 1593-1598.

    Google Scholar 

  • Scheer H. 1991 Chlorophylls CRC Press, London.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tomonou, Y., Amao, Y. Visible light induced hydrogen production with Mg chlorophyll-a from spirulina and colloidal platinum. Biometals 15, 391–395 (2002). https://doi.org/10.1023/A:1020213122186

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1020213122186

Navigation