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A structural study on gallium and indium β-diketonates

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Abstract

In an attempt to prepare pentacoordinate chlorobis(β-diketonato) gallium(III) and indium(III) complexes only the corresponding tris-products, Ga(PhCOCHCOPh)3 (1), Ga(tBuCOCHCOtBu)3 (1a), and In(PhCOCHCOPh)3 (2), could be isolated. The crystal and molecular structures of 1 and 2 were determined. Both the complexes were found to have triclinc crystal system, with P1 space group. Cell parameters: 1 – a = 9.913(3) Å, b = 10.534(6) Å, c = 18.05(2) Å, α = 93.86(5)°, β = 94.40(4)°, γ = 106.58(4)°, V = 1805(2) Å3, z = 2; 2 – a = 10.507(3) Å, b = 11.448(3) Å, c = 16.322(4) Å, α = 107.38(2)°, β = 97.38(2)°, γ = 102.23(2)°, V = 1792(1) Å3, z = 2.

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Authors and Affiliations

  1. Chemistry Department, Post Graduate College, Ghazipur, 223 002, India

    Subrato Bhattacharya

  2. Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi, 221 005, India

    Sudha Singh & Vishnu D. Gupta

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  1. Subrato Bhattacharya
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  2. Sudha Singh
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  3. Vishnu D. Gupta
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Correspondence to Subrato Bhattacharya.

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Bhattacharya, S., Singh, S. & Gupta, V.D. A structural study on gallium and indium β-diketonates. Journal of Chemical Crystallography 32, 299–305 (2002). https://doi.org/10.1023/A:1020205508054

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