Abstract
The performances and applicability of a diffusion tubesampler for the simultaneous measurements of NO2 andSO2 in ambient air were evaluated. SO2 andNO2are collected by the passive sampler using triethanolamine astrapping agent and are determined as sulphate and nitrite withion chromatography. The detection limit (2.3 μg m-3 ofNO2 and 4.2 μg m-3 of SO2 for two weekssampling) is adequate for the determination of concentrationsin urban and industrial areas. Precision of the method as RSDis in mean 5% for NO2 and 12% for SO2 at theconcentration levels in urban areas. Calibration of the methodwas performed in the field conditions by comparison between theresponses of sampler and the concentrations measured by thecontinuous monitors. High degree of linearity (correlationcoefficients > 0.8) is found between the passive sampler tubeand the continuous monitor data for both NO2 and SO2.To reduce the wind velocity influence on passive sampling ofdiffusion tubes, a protective shelter was tested in this study.The overall uncertainty of one measure for the optimised methodis estimated at 5 μg m-3 for NO2 and 6μg m-3 for SO2. Suitability of this passivesampling method for air pollution monitoring in urban areas wasdemonstrated by the results shown in this paper on a campaigncarried out in the French agglomeration.
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Plaisance, H., Sagnier, I., Saison, J.Y. et al. Performances and Application of a Passive Sampling Method for the Simultaneous Determination of Nitrogen Dioxide and Sulfur Dioxide in Ambient Air. Environ Monit Assess 79, 301–315 (2002). https://doi.org/10.1023/A:1020205230396
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DOI: https://doi.org/10.1023/A:1020205230396