Abstract
The gelation in liquid glass–based potassium silicophosphate solutions prepared at different pH is studied. The phosphorus pentoxide content entering into the gel composition is determined. The physicochemical transformations during the heat treatment of gel powders are investigated by X-ray powder diffraction and differential thermal analyses.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Kuznetsova, L.A., Golubeva, T.Yu., Khashkovskii, S.V., and Belyustin, A.A., Enamel Compositions Based on Gel-Forming Solutions of Alkali Silicates, Zh. Prikl. Khim. (St. Petersburg), 1998, vol. 71, no. 4, pp. 553–555.
Kuznetsova, L.A., Golubeva, T.Yu., and Khashkovskii, S.V., Composite Materials and Coatings Based on Aqueous Silicate Solutions, Trudy XVII soveshchaniya po temperaturoustoichivym funktsional'nym Pokrytiyam (Proceedings of the XVII Conference on Thermally Stable Functional Coatings), St. Petersburg, 1997, part I, pp. 93–98.
Kuznetsova, L.A., Golubeva, T.Yu., and Khashkovskii, S.V., Chemically Stable Enamels Produced by Sol-Gel Method, Trudy XVII soveshchaniya po temperaturoustoichivym funktsional'nym pokrytiyam (Proceedings of the XVII Conference on Thermally Stable Functional Coatings), St. Petersburg, 1997, part II, pp. 77–79.
Korneev, V.I. and Danilov, V.V., Proizvodstvo i primenenie rastvorimogo stekla (Manufacturing and Application of Liquid Glass), Leningrad: Stroiizdat, 1991.
Vakhula, Ya.I., Yashchishin, I.N., and Semchuk, O.R., Gelation in Multicomponent Colloidal Solutions Based on Potassium Liquid Glass, Fiz. Khim. Stekla (in press).
Petrovskii, G.T. and Dotsenko, A.V., Vitreous and Glass-Ceramic Optical Materials, Opt. Zh., 1993, no. 11, pp. 69–75.
Bol'shii, Ya.Ya., Silicophosphate Glasses and Materials on Their Base, Abstract of Doctoral Dissertation, Leningrad, 1986.
Lazernye fosfatnye stekla (Laser Phosphate Glasses), Zhabotinskii, M.E., Ed., Moscow: Nauka, 1980.
Pavlushkina, T.K., A Study of Structure and Properties of Multicomponent Phosphorus-Containing Glasses, Tezisy dokladov XV Mezhdunarodnogo kongressa po steklu (Abstracts of Papers, XV International Congress on Glass), Leningrad: Nauka, 1989, vol. 28, pp. 349–352.
Krivovyazov, E.L., Neorganicheskie polimernye fosfaty (Inorganic Polymeric Phosphates), Moscow: Znanie, 1978.
Van Wazer, J.R., Phosphorus and Its Compounds, New York: Interscience, 1958. Translated under the title Fosfor i ego soedineniya, Moscow: Mir, 1962.
Praktikum po fiziko-khimicheskim metodam analiza (Laboratory Manual for Physicochemical Methods of Analysis), Petrukhin, O.M., Ed., Moscow: Khimiya, 1987.
Vitinya, I.A., Lagzdinya, S.E., Kramskaya, O.A., and Sedmalis, U.Ya., Physicochemical Properties and Structure of Potassium Silicophosphate Glasses, in Neorganicheskie stekla, pokrytiya i materialy. Sbornik nauchnykh trudov (Inorganic Glasses, Coatings, and Materials: A Collection of Papers), Riga: RPI, 1989, pp. 69–75.
Mezhinskii, G.Kh., Sedmalis, U.Ya., Beierbakha, I.R., and Buka, I.I., Structural Features of Silicophosphate Glasses Synthesized by Sol-Gel Method, in Neorganicheskie stekla, pokrytiya i materialy. Sbornik nauchnykh trudov (Inorganic Glasses, Coatings, and Materials: A Collection of Papers), Riga: RPI, 1989, pp. 74–79.
Lepilina, R.G. and Smirnova, N.M., Termogrammy neorganicheskikh fosfatnykh soedinenii. Spravochnik (Thermograms of Inorganic Phosphate Compounds: A Handbook), Leningrad: Nauka, 1984.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Vakhula, Y.I., Semchuk, O.P. & Kozii, O.I. The Role of the Phosphate Component in the Gelation of a Potassium Silicophosphate Solution. Glass Physics and Chemistry 28, 256–259 (2002). https://doi.org/10.1023/A:1019970514354
Issue Date:
DOI: https://doi.org/10.1023/A:1019970514354