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Thermochemical behaviour of crown ethers aqueous organic solvents: Part IV: Propanol and acetonitrile with water mixtures

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Abstract

Enthalpies of solution of 15-crown-5 (15C5) in the mixtures of water with acetonitrile (AN) or propan-1-ol (PrOH) and benzo-15-crown-5 ether (B15C5) in the PrOH-water mixtures have been measured at 298.15 K. The values of standard enthalpies of solution of 15C5 are negative in the mixtures of water with AN within the whole range of mixture composition and in the mixtures water-PrOH for water content xw>0.1 and those of B15C5 are positive (except the standard enthalpy of B15C5 in pure water) in the system water-PrOH. The results of the calorimetric measurements together with the earlier data for B15C5 in water-acetonitrile mixtures are discussed with regard to the intermolecular interactions that occur in these systems.

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References

  1. H. Piekarski and M. Jóźwiak, J. Therm. Anal., 48 (1997) 1283.

    Google Scholar 

  2. M. Jóźwiak and H. Piekarski, J. Mol. Liquids, 81 (1999) 63.

    Google Scholar 

  3. M. Jóźwiak, J. Mol. Liquids, 81 (1999) 261.

    Google Scholar 

  4. M. Jóźwiak and H. Piekarski, J. Mol. Liquids, 95 (2002) 313.

    Google Scholar 

  5. J. J. Christensen, D. J. E. Eatough and R. M. Izatt, Chem. Rev., 74 (1974) 351.

    Google Scholar 

  6. R. M. Izatt, J. S. Bradshaw, S. A. Nielsen, J. D. Lamb and J. J. Christensen, Chem. Rev., 85 (1985) 271.

    Google Scholar 

  7. Y. Takeda, K. Katsuta, Y. Inoue and T. Hakushi, Bull. Chem. Soc. Jpn., 61 (1988) 627.

    Google Scholar 

  8. Y. Takeda and T. Kumazawa, Bull. Chem. Soc. Jpn., 61 (1988) 655.

    Google Scholar 

  9. R. M. Izatt, K. Pawlak and J. S. Bradshaw, Chem. Rev., 91 (1991) 1721.

    Google Scholar 

  10. R. M. Izatt, J. S. Bradshaw, K. Pawlak, R. L. Bruening and B. J. Tarbet, Chem. Rev., 92 (1992) 1261.

    Google Scholar 

  11. R. M. Izatt, K. Pawlak and J. S. Bradshaw, Chem. Rev., 95 (1995) 2529.

    Google Scholar 

  12. M. J. Mastroianni, M. J. Pikal and S. Lindenbaum, J. Phys. Chem., 76 (1972) 3050.

    Google Scholar 

  13. A. K. Covington and K. E. Newman, Adv. Chem. Ser., 155 (1976) 153.

    Google Scholar 

  14. K. Remerie and J. B. F. N. Engberts, J. Phys. Chem., 87 (1983) 5449.

    Google Scholar 

  15. R. W. Balk and G. Somsen, J. Phys. Chem., 89 (1985) 5093.

    Google Scholar 

  16. J. F. Coetzee, Pure Appl. Chem., 13 (1966) 429.

    Google Scholar 

  17. H. Piekarski and D. Waliszewski, J. Thermal Anal., 47 (1996) 1639.

    Google Scholar 

  18. C. de Visser and G. Somsen, J. Phys. Chem., 78 (1974) 1719.

    Google Scholar 

  19. W. J. M. Heuvesland, C. de Visser and G. Somsen, J. Phys. Chem., 82 (1978) 29.

    Google Scholar 

  20. C. de Visser and G. Somsen, J. Solution Chem., 3 (1974) 847.

    Google Scholar 

  21. C. de Visser, W. J. M. Heuvesland and G. Somsen, J. Solution Chem., 4 (1975) 311.

    Google Scholar 

  22. W. J. M. Heuvesland and G. Somsen, J. Chem. Thermodyn., 8 (1976) 873.

    Google Scholar 

  23. W. J. M. Heuvesland, C. de Visser, G. Somsen, A. LoSurdo and W.-Y. Wen, J. Solution Chem., 8 (1979) 25.

    Google Scholar 

  24. W. J. M. Heuvesland, Hydrophobic hydration in aqueous solvent mixtures, Thesis, Vrije Universiteit, Amsterdam 1980.

    Google Scholar 

  25. W. J. M. Heuvesland, M. Bloemendal, C. de Visser and G. Somsen, J. Phys. Chem., 84 (1980) 2391.

    Google Scholar 

  26. A. C. Rouw and G. Somsen, J. Chem. Thermodynamics, 13 (1981) 67.

    Google Scholar 

  27. A. C. Rouw and G. Somsen, J. Solution Chem., 8 (1981) 533.

    Google Scholar 

  28. A. Rouw and G. Somsen, J. Chem. Soc. Faraday Trans. 1, 78 (1982) 3397.

    Google Scholar 

  29. G. Somsen, Pure and Appl. Chem., 65 (1993) 983.

    Google Scholar 

  30. G. Somsen, in Thermochemistry and its applications to chemical and biological systems, D. Reidel 1984, p. 425.

  31. M. J. Mastroianni, M. J. Pikal and S. Lindenbaum, J. Phys. Chem., 76 (1972) 3050.

    Google Scholar 

  32. A. K. Covington and K. E. Newman, Adv. Chem. Ser., 155 (1976) 153.

    Google Scholar 

  33. K. Remerie and J. B. F. N. Engberts, J. Phys. Chem., 87 (1983) 5449.

    Google Scholar 

  34. H. S. Gold and M. R. Rice, Talanta, 29 (1982) 637.

    Google Scholar 

  35. P. A. Mosier-Boss and A. I. Popov, J. Am. Chem. Soc., 107 (1985) 6168.

    Google Scholar 

  36. D. Peeters and P. Huyskens, J. Mol. Struct., 300 (1993) 539.

    Google Scholar 

  37. K. W. Morcom and R. W. Smith, J. Chem. Thermodynamics, 1 (1969) 503.

    Google Scholar 

  38. K. Dimroth, C. Reichardt, T. Siepmann and F. Bohlmann, Liebigs Ann. Chem., 661 (1963) 1.

    Google Scholar 

  39. M. J. Kamlet and R. W. Taft, J. Am. Chem. Soc., 98 (1976) 377.

    Google Scholar 

  40. M. J. Kamlet, J.-L. M. Abboud, M. H. Abraham and R. W. Taft, J. Org. Chem., 48 (1983) 2877.

    Google Scholar 

  41. T. M. Krygowski, P. K. Wrona, U. Zielkowska and Ch. Reichardt, Tetrahedron, 41 (1985) 4519.

    Google Scholar 

  42. W. R. Fawcett and M. Krygowski, Aust. J. Chem., 28 (1975) 2115.

    Google Scholar 

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  1. Department of Physical Chemistry, University of Łódź, Pomorska 165, 90-236, Łódź, Poland

    M. Jóźwiak & H. Piekarski

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  1. M. Jóźwiak
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  2. H. Piekarski
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Jóźwiak, M., Piekarski, H. Thermochemical behaviour of crown ethers aqueous organic solvents: Part IV: Propanol and acetonitrile with water mixtures. Journal of Thermal Analysis and Calorimetry 69, 291–300 (2002). https://doi.org/10.1023/A:1019918613889

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