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Structural Thermo‐ and Phototransformations of Oxaindane Spiropyrans Adsorbed on Silver Films

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Abstract

Using giant Raman scattering spectroscopy methods, we have studied the structure and also the thermo‐ and phototransformations of dimethylphthalanspirobenzopyran (PhSBP) adsorbed on the surface of silver films. It is shown that on adsorption of PhSBP from ethanol solutions, on the surface of the silver films there are predominantly open forms of molecules which do not exhibit photochromic properties. It is established that cooling of the specimen to 77 K initiates thermoreversible reconstruction of the adsorption layer with formation of the aggregates of the PhSBP molecules. These reversible structural changes in frozen specimens are enhanced on exposure to the light of a visible range.

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REFERENCES

  1. A. S. Kholmanskii and K. M. Dyumaev, Usp. Khim., 56, 241–276 (1987).

    Google Scholar 

  2. R. K. Chang and T. E. Furtak (eds.), Surface Enhanced Raman Scattering [Russian translation], Moscow (1984).

  3. N. A. Voloshin, Spiropyrans of the 2-Heteroindane Series, Abstract of Candidate Dissertation(in Chemistry), Rostov-on-Don (1977).

  4. N. A. Voloshin, N. E. Shelepin, and V. I. Minkin, Spiropyrans of the 2-Oxaindane Series Manifesting Photochromic Properties and Method of Obtaining Them, USSR Inventor's Certificate No. 518491 (1977).

  5. A. Feofanov, A. Ianoul, E. Kryukov, S. Maskevich, G. Vasilyuk, L. Kivach, and I. Nabiev, Anal. Chem., 69, 3731–3740 (1997).

    Google Scholar 

  6. K. Yoda, T. Ohzeki, T. Yuzawa, and H. Takahashi, Spectrochim. Acta, 45A, 855–862 (1989).

    Google Scholar 

  7. S. A. Maskevich, G. T. Vasilyuk, G. A. Gachko, L. N. Kivach, and D. A. Oparin, Zh. Prikl. Spektrosk., 63, 87–90 (1996).

    Google Scholar 

  8. P. Fruit, R. Gauton, and C. Audic, Bull. Soc. Chim. France, 5, 2237–2242 (1968).

    Google Scholar 

  9. W. Dai and C. Xue, Spectrosc. Lett., 28, 735–746 (1995).

    Google Scholar 

  10. S. Schneider, H. Grau, and J. Ringer, Mol. Cryst. Liquid Cryst. Sci. Technol., 246, 267–274 (1994).

    Google Scholar 

  11. J. Aubard, C. Mbossa, J. P. Bertinge, R. Dubest, G. Levi, E. Boshet, and R. Guglielmetti, Mol. Cryst. Liquid Cryst. Sci. Technol., 246, 275–278 (1994).

    Google Scholar 

  12. H. Eckhard, A. Bose, and V. A. Krongaur, Polymer, 28, 1959–1964 (1987).

    Google Scholar 

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Authors and Affiliations

  1. Grodno State University, 22 Ozheshko Str., Grodno, 230023, Belarus

    G. T. Vasilyuk, S. A. Maskevich, S. G. Podtynchenko & V. I. Stepuro

  2. Scientific‐Research Institute of Physical and Organic Chemistry, Rostov State University, Russia

    B. S. Luk'yanov & Yu. S. Alekseenko

Authors
  1. G. T. Vasilyuk
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  2. S. A. Maskevich
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  3. S. G. Podtynchenko
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  4. V. I. Stepuro
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  5. B. S. Luk'yanov
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  6. Yu. S. Alekseenko
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Correspondence to G. T. Vasilyuk.

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Vasilyuk, G.T., Maskevich, S.A., Podtynchenko, S.G. et al. Structural Thermo‐ and Phototransformations of Oxaindane Spiropyrans Adsorbed on Silver Films. Journal of Applied Spectroscopy 69, 344–350 (2002). https://doi.org/10.1023/A:1019786729335

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