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Nickel(II) Diisobutyldithiophosphinate Complexes with Hexamethylenetetramine and Triethylenediamine: Synthesis and Properties. Crystal and Molecular Structure of [Ni2(C6H12N4){(i-C4H9)2PS2}4]

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Abstract

The paramagnetic compounds [Ni2(HMTA)(i-Bu2PS2)4] (I) and [Ni2(TEDA)(i-Bu2PS2)4] (II) (μeff = 3.11 and 3.23 μB, respectively) were synthesized by reacting diamagnetic Ni(i-Bu2PS2)2 with hexamethylenetetramine (HMTA) and triethylenediamine (TEDA) in ethanol. The crystal structure of I was established by single-crystal X-ray diffraction analysis (CAD4 diffractometer, MoK α radiation, 1483 F hkl, R = 0.0648). The crystals are monoclinic: a = 35.212(7) Å, b = 9.313(2) Å, c = 22.622(5) Å; β = 129.97(3)°, V = 5685(2) Å3, Z = 4, ρ(calcd) = 1.281 g/cm3, space group C2/c. The structure is built of discrete binuclear molecules. The coordination polyhedron of the Ni atom is a distorted tetragonal pyramid with four S atoms of two bidentate cyclic ligands i-Bu2PS2 – in the base and the N atom of the bidentate bridging ligand HMTA at the axial vertex. Complexes I and II have similar electronic reflection spectra, which agrees with the C 4v symmetry of the ligand field.

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REFERENCES

  1. Wasson, J.R., Woltermann, G.M., and Stoklosa, H.J., Top. Curr. Chem., 1973, vol. 35, nos. 3-4, p. 65.

    Google Scholar 

  2. Larionov, S.V., Kokina, T.E., Glinskaya, L.A., and Klevtsova, R.F., Koord. Khim., 2001, vol. 27, no. 7, p. 498.

    Google Scholar 

  3. Glinskaya, L.A., Klevtsova, R.F., Kokina, T.E., and Larionov, S.V., Zh. Strukt. Khim., 2001, vol. 42, no. 6, p. 1174.

    Google Scholar 

  4. Graham, P.M., Pike, R.D., Sabat, M., et al., Inorg. Chem., 2000, vol. 39, no. 22, p. 5121.

    Google Scholar 

  5. Carlucci, L., Ciani, G., Proserpio, D.M., and Sironi, A., Inorg. Chem., 1997, vol. 36, no. 8, p. 1736.

    Google Scholar 

  6. Mak, T.C.W., Inorg. Chim. Acta, 1984, vol. 84, no. 1, p. 19.

    Google Scholar 

  7. Diemert, K. and Kuchen, W., Chem. Ber., 1971, vol. 104, no. 8, p. 2592.

    Google Scholar 

  8. Rudzinski, W., Shiro, M., and Fernando, Q., Anal. Chem., 1975, vol. 47, no. 7, p. 1194.

    Google Scholar 

  9. Sheldrick, G.M., SHELX97, Release 97-2: Program for Solution and Refinement of Crystal Structures, Göttingen: Univ. of Göttingen, 1998.

    Google Scholar 

  10. Bogdanov, A.P. and Zelentsov, V.V., Zh. Neorg. Khim., 1977, vol. 22, no. 10, p. 2611.

    Google Scholar 

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Authors and Affiliations

  1. Siberian Division, Russian Academy of Sciences, Institute of Inorganic Chemistry, pr. Akademika Lavrent'eva 3, Novosibirsk, 630090, Russia

    S. V. Larionov, T. E. Kokina, L. A. Glinskaya & R. F. Klevtsova

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    S. V. Larionov, T. E. Kokina, L. A. Glinskaya & R. F. Klevtsova

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  1. S. V. Larionov
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  2. T. E. Kokina
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  3. L. A. Glinskaya
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  4. R. F. Klevtsova
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Larionov, S.V., Kokina, T.E., Glinskaya, L.A. et al. Nickel(II) Diisobutyldithiophosphinate Complexes with Hexamethylenetetramine and Triethylenediamine: Synthesis and Properties. Crystal and Molecular Structure of [Ni2(C6H12N4){(i-C4H9)2PS2}4]. Russian Journal of Coordination Chemistry 28, 560–564 (2002). https://doi.org/10.1023/A:1019757629587

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