Abstract
The Voronoi–Dirichlet polyhedra (VDP) and the method of intersecting spheres were used to perform a crystal-chemical analysis of all compounds studied to date whose structures contain rhodium atoms surrounded by oxygen atoms. All Rh atoms were found to have a coordination number (CN) equal to 6 and to form coordination polyhedra of two types, namely, the distorted octahedra RhO6 and RhO5Rh. A coordination number of 6 was found for all Rh(IV), Rh3.5+, and Rh(III) atoms, while a CN of 5+1 was found typical only of Rh2.5+ and Rh(II) atoms. The effect of the valence state of Rh on the main features of their crystal-chemical role in the structures is considered in terms of the 18-electron rule.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Serezhkina, L.B. and Serezhkin, V.N., Koord. Khim., 2000, vol. 26, no. 12, p. 933.
Serezhkin, V.N. and Serezhkina, L.B., Koord. Khim., 2002, vol. 28, no. 3, p. 212.
Serezhkin, V.N., Mikhailov, Yu.N., and Buslaev, Yu.A., Zh. Neorg. Khim., 1997, vol. 42, no. 12, p. 2036.
Inorganic Crystal Structure Database. Release 2000/1, Gaithersburg: FIZ Karlsruhe & NIST, 2000.
Cambridge Structural Database System. Version 5/20, Cambridge Crystallographic Data Centre, 2000.
Blatov, V.A., Shevchenko, A.P., and Serezhkin, V.N., Koord. Khim., 1999, vol. 25, no. 7, p. 483.
Shannon, R.D., Solid State Commun., 1968, vol. 6, no. 1, p. 139.
Chamberland, B.L. and Anderson, J.B., J. Solid State Chem., 1981, vol. 39, no. 1, p. 114.
Munez, P., Trail, S., and zur Loye, H-C., J. Solid State Chem., 1997, vol. 130, no. 1, p. 35.
Omaly, J., Kohlmuller, R., Batail, P., and Chevalier, R., Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1980, vol. 36, no. 5, p. 1040.
Ziolkowski, J.J., Moszner, M., and Glowiak, T., J. Chem. Soc., Chem. Commun., 1977, p. 760.
Siegrist, T., Larson, E.M., and Chamberland, B.L., J. Alloys Compd., 1994, vol. 210, no. 1, p. 13.
Blatov, V.A., Pol'kin, V.A., and Serezhkin, V.N., Kristallografiya, 1994, vol. 39, no. 3, p. 457.
Serezhkin, V.N. and Buslaev, Yu.A., Zh. Neorg. Khim., 1997, vol. 42, no. 7, p. 1180.
Crawford, C.A., Day, E.F., Saharan, V.P., et al., J. Chem. Soc., Chem. Commun., 1996, p. 1113.
Minkin, V.I., Simkin, B.Ya., and Minyaev, R.M., Teoriya stroeniya molekul (Theory of Molecular Structure), Rostov-on-Don: Feniks, 1997, p. 448.
Serezhkin, V.N. and Serezhkina, L.B., Koord. Khim., 1998, vol. 24, no. 3, p. 194.
Dikareva, L.M., Zefirov, Yu.V., Zhilyaev, A.N., et al., Zh. Neorg. Khim., 1987, vol. 32, no. 1, p. 118.
Claridge, J.B. and zur Loye, H.-C., Chem. Mater., 1998, vol. 10, no. 9, p. 2321.
Blatov, V.A., Pogildyakova, L.V., and Serezhkin, V.N., Acta Crystallogr., Sect. B: Struct. Sci., 1999, vol. 55, no. 1, p. 139.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Serezhkin, V.N., Serezhkina, L.B. Stereochemistry of Rhodium in Oxygen-Containing Compounds. Russian Journal of Coordination Chemistry 28, 581–586 (2002). https://doi.org/10.1023/A:1019713814566
Issue Date:
DOI: https://doi.org/10.1023/A:1019713814566