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Role of Epoxides in the Oxidation of Allyl Alcohol, Allyl Formate, and Allyl Acetate in Acetic Acid

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Abstract

The formation of epoxy derivatives as intermediate products in the oxidation of allyl alcohol, allylformate, allyl acetate in acetic acid was proved. Intermediate epoxy compounds undergo further trans-formations: They react with acetic acid to give glycerol esters or are converted into polyethers of glyceroland its esters. The rate constants for transformations of 2,3-epoxypropanol, 2,3-epoxypropyl formate, and 2,3-epoxypropyl acetate along these pathways were measured. Higher selectivity of glycerol ester formation from allyl formate was substantiated.

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  1. Lviv State Agrarian University, ul. Sagaidachnogo 14b, Lviv, 79014, Ukraine

    E. V. Fedevich

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  1. E. V. Fedevich
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Fedevich, E.V. Role of Epoxides in the Oxidation of Allyl Alcohol, Allyl Formate, and Allyl Acetate in Acetic Acid. Russian Journal of Organic Chemistry 38, 632–635 (2002). https://doi.org/10.1023/A:1019694502327

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  • DOI: https://doi.org/10.1023/A:1019694502327

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