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Thermodynamics and Electrostatics of a Metal-Solution Interface

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Abstract

Based on the fundamental equations of thermodynamics and electrostatics, quantitative and qualitative analysis of the properties of a metal-electrolyte boundary showed that one should choose electronic rather than conventional models of the double layer structure.

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REFERENCES

  1. Drude, P., Ann.Phys., 1900, vol. 1, p. 566.

    Google Scholar 

  2. Gouy, G., J. Phys. Radium., 1910, vol. 9, p. 457.

    Google Scholar 

  3. Chapman, D.L., Philos. Mag., 1913, vol. 25, p. 475.

    Google Scholar 

  4. Helmholtz, H., Wied. Ann., 1879, vol. 7, p. 337.

    Google Scholar 

  5. Yeager, E., Surf. Sci., 1980, vol. 101, p. 1.

    Google Scholar 

  6. Frenkel, J.I., Phil. Mag., 1917, vol. 33, no. 96, p. 297.

    Google Scholar 

  7. Rice, O.K., Phys. Rev., 1928, vol. 31, p. 1051.

    Google Scholar 

  8. Kuklin, R.N., Elektrokhim., 1976, vol. 14, p. 380.

    Google Scholar 

  9. Salem, P.P., Zh. Fiz. Khim., 1980, vol. 54, p. 212.

    Google Scholar 

  10. Badiali, J.P. and Goodisman, J.J., J. Electroanal. Chem., 1978, vol. 91, p. 151.

    Google Scholar 

  11. Kornyshev, A.A. and Vorotyntsev, M.A., Surf. Sci., 1980, vol. 101, p. 23.

    Google Scholar 

  12. Martynov, G.A. and Salem, R.R., Electrical Double Layer at a Metal-Dilute Electrolyte Solution Interface, New York: Springer, 1983.

    Google Scholar 

  13. Martynov, G.A. and Salem, R.R., J. Canad. Chem., 1984, vol. 64, p. 1148.

    Google Scholar 

  14. Martynov, G.A. and Salem, R.R., Elektrokhim., 1983, vol. 19, p. 1060.

    Google Scholar 

  15. Martynov, G.A. and Salem, R.R., Zh. Fiz. Khim., 1984, vol. 58, p. 567.

    Google Scholar 

  16. Theory of Inhomogeneous Electron Gas, Lundqvist, S. and March, N.H., Eds., New York: Plenum, 1983.

    Google Scholar 

  17. Ukhov, V.F. et al., Elektronno-statisticheskaya teoriya metallov i ionnykh kristallov (Electronic and Statistical Theory of Metals and Ionic Crystals), Moscow: Nauka, 1982.

    Google Scholar 

  18. Stern, O., Z. Elektrochem., 1924, vol. 30, p. 508.

    Google Scholar 

  19. Grahame, D.C., J. Electrochem. Soc., 1951, vol. 98, p. 3.

    Google Scholar 

  20. Tamm, I.E., Osnovy elektrichestva (The Principles of Electricity Theory), Moscow: Nauka, 1976.

    Google Scholar 

  21. Khoriuti, D. and Toya, T., Solid State Surface Science, Green, N., Ed., New York: Marcel Dekker, 1969.

    Google Scholar 

  22. Parsons, R., J. Electroanal. Chem., 1975, vol. 59, p. 229.

    Google Scholar 

  23. Fawcett, W.R., Levine, S., de Nobriga, R.M., and McDonald, A.C., J. Electroanal. Chem., 1980, vol. 8, p. 163.

    Google Scholar 

  24. Bockris, J.O'M., Devanathan M.A.V., and Muller K), Proc. R. Soc. London, Ser. A, 1963, vol. 274, p. 55.

    Google Scholar 

  25. Levine, S., Bell, G.M., and Smith, A.L., J. Phys. Chem., 1969, vol. 73, p. 3534.

    Google Scholar 

  26. Damaskin, B.B. and Frumkin, A.N., Electrochem. Acta, 1974, vol. 19, p. 173.

    Google Scholar 

  27. Damaskin, B.B., Pal'm, U.V., and Sal've, M.D., Elektrokhim., 1976, vol. 12, p. 232.

    Google Scholar 

  28. Oldkham K.B. and Parsons, R., Elektrokhim., 1977, vol. 13, p. 866.

    Google Scholar 

  29. Fawcett, W.R., J. Phys. Chem., 1978, vol. 82, p. 1385.

    Google Scholar 

  30. Borkovskaya Z. and Fossett, V.R., Elektrokhim., 1980, vol. 16, p. 1692.

    Google Scholar 

  31. Bokris, J.O'M. and Habib, M.A., J. Electroanal. Chem., 1975, vol. 65, p. 473.

    Google Scholar 

  32. Fawcett, W.R., Ikeda, B.H., and Sollak, J.B., J. Canad. Chem., 1979, vol. 57, p. 2268.

    Google Scholar 

  33. Frumkin, A.N., Usp. Khim., 1946, vol. 15, p. 385.

    Google Scholar 

  34. Ershler, V.A., Usp. Khim., 1952, vol. 21, p. 237.

    Google Scholar 

  35. Brodskii, A.M., Gurevich, Yu.Ya., Pleskov, Yu.V., and Rotenberg, Z.A., Sovremennaya fotoelektrokhimiya: Fotoemissionnye yavleniya (Modern Photoelectrochemistry: Photoemission Phenomena), Moscow: Nauka, 1974.

    Google Scholar 

  36. Frumkin, A.N., Potentsialy nulevogo zaryada (Zero-Charge Potentials), Moscow: Nauka, 1979.

    Google Scholar 

  37. Pal'm, U.V., Dr. Sci. (Chem.) Dissertation, Moscow, 1974.

  38. Payne, R., J. Phys. Chem., 1967, vol. 71, p. 1546.

    Google Scholar 

  39. Karpachev, S.V. and Stromberg, A.G., Zh. Fiz. Khim., 1944, vol. 18, p. 47.

    Google Scholar 

  40. Budevskii, E., Vitanov, T., Sevast'yanov, E.S., and Panov, A., Elektrokhim., 1969, vol. 5, p. 90.

    Google Scholar 

  41. Andrusev, M.M., Ershler, A.B., and Tedoradze, G.A., Elektrokhim., 1970, vol. 6, p. 1163.

    Google Scholar 

  42. Kheifets, V.Ya. and Krasikov, B.S., Dokl. Akad. Nauk SSSR, 1956, vol. 109, p. 586.

    Google Scholar 

  43. Bartenev, V.Ya., Sevast'yanov, E.S., and Leikis, D.I., Elektrokhim., 1969, vol. 5, p. 149; p. 1502.

    Google Scholar 

  44. Hampson, H.A. and Latham, R.J., J. Electroanal. Chem., 1971, vol. 34, p. 57.

    Google Scholar 

  45. Grigor'ev, N.V. and Bulavka, V.A., Elektrokhim., 1976, vol. 12, p. 1103.

    Google Scholar 

  46. Frumkin, A.N., Polyanovskaya, N.S., and Grigor'ev, N.B., Dokl. Akad. Nauk SSSR, 1964, vol. 157, p. 1455.

    Google Scholar 

  47. Gurevich, Yu.Ya. and Pleskov, Yu.V., Fotoelektrokhimiya poluprovodnikov, Moscow: Nauka, 1983. Translated under the title Semiconductor Photoelectrochemistry, New York: Consultants Bureau, 1986.

    Google Scholar 

  48. Sychev, V.V., Differentsial'nye uravneniya termodinamiki (Differential Equations of Thermodynamics), Moscow: Nauka, 1981, vol. 1.

    Google Scholar 

  49. Vonsovskii, S.V., Magnetizm, Moscow: Nauka, 1979. Translated under the title Magnetism, New York: Wiley, 1984, vols. 1-2.

    Google Scholar 

  50. Pein, R., Techniques of Electrochemistry, Yeger, E., Ed., New York: Wiley, 1972.

    Google Scholar 

  51. Salem, R.R., Zh. Fiz. Khim., 1988, vol. 62, p. 1582.

    Google Scholar 

  52. Smirnov, M.V. and Stepanov, V.P., Fizicheskaya khimiya. Sovremennye problemy (Physical Chemistry. Modern Problems), Moscow: Khimiya, 1988.

    Google Scholar 

  53. Barradas, R.G. and Kimmerle, F.M., Can. J. Chem., 1967, vol. 45, p. 108.

    Google Scholar 

  54. Grahame, D.C., J. Am. Chem. Soc., 1954, vol. 76, p. 4821.

    Google Scholar 

  55. Bakhshiev, N.G., Spektroskopiya mezhmolekulyarnykh vzaimodeistvii (Spectroscopy of Intermolecular Interactions), Leningrad: Nauka, 1972.

    Google Scholar 

  56. Delahay, P., Double Layer and Electrode Kinetics, New York: Interscience Publishers a Division of John Wiley, 1965.

    Google Scholar 

  57. Dorfman, Ya.G., Diamagnetizm i khimicheskaya svyaz' (Diamagnetism and Chemical Bond), Moscow: Izd. Fiz.-Mat. Literatury, 1961.

    Google Scholar 

  58. Kittel, C., Introduction to Solid State Physics, New York: Wiley, 1974.

    Google Scholar 

  59. Grahame, D.C., J. Am. Chem. Soc., 1957, vol. 79, p. 2093.

    Google Scholar 

  60. Sokolov, Yu.M., Tedoradze, G.A., and Arakelyan, V.A., Elektrokhim., 1973, vol. 9, no. 4, p. 554.

    Google Scholar 

  61. Delahay, P., de Levie, R., and Giviliam, A.M., Electrochim. Acta, 1966, vol. 11, p. 1141.

    Google Scholar 

  62. Takachashi, K. and Tamamushi, R., Electrochim. Acta, 1971, vol. 16, p. 875.

    Google Scholar 

  63. Ariel, M. and Nemirovsky, J., Electrochim. Acta, 1972, vol. 17, p. 1977.

    Google Scholar 

  64. Dzhaparidze, Dzh.I. and Chagelashvili, V.P., Dvoinoi sloi i adsorbtsiya na tverdykh elektrodakh (Double Layer and Adsorption on Solid Electrodes), Tartu: Tartusskii Gos. Univ., 1975, vol. 4, p. 89.

    Google Scholar 

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  1. Russian Academy of Sciences, High Chemistry College, Miusskaya pl. 9, Moscow, 125047, Russia

    R. R. Salem

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Salem, R.R. Thermodynamics and Electrostatics of a Metal-Solution Interface. Protection of Metals 38, 297–309 (2002). https://doi.org/10.1023/A:1019692430804

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