Abstract
Chlorolysis of β-functionalized alkyl polyfluoroalkenyl sulfides giving rise to β-functionalized polyfluoroalkenesulfenyl chlorides was examined. β-Cyano-containing sulfenyl chlorides underwent intramolecular cyclization at the nitrile group to form substituted isothiazoles.
Similar content being viewed by others
References
A. Yu. Sizov, A. F. Kolomiets, and A. V. Fokin, Usp. Khim., 1992, 61, 940 [Russ. Chem. Rev., 1992, 61 (Engl. Transl.)].
V. Ya. Popkova, Dr. Sc. (Chem.) Thesis, A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow, 1995, 88 pp. (in Russian).
R. A. Bekker, L. A. Rozov, and V. Ya. Popkova, Izv. Akad. Nauk SSSR, Ser. Khim., 1983, 2575 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1983, 32, 2317 (Engl. Transl.)].
A. N. Kovregin, A. Yu. Sizov, A. F. Ermolov, and A. F. Kolomiets, Izv. Akad. Nauk, Ser. Khim., 2000, 1770 [Russ. Chem. Bull., Int. Ed., 2000, 49, 1749].
A. N. Kovregin, A. Yu. Sizov, and A. F. Ermolov, Izv. Akad. Nauk, Ser. Khim., 2001, 1197 [Russ. Chem. Bull., Int. Ed., 2001, 50, 1255].
A. N. Kovregin, A. Yu. Sizov, and A. F. Ermolov, Izv. Akad. Nauk, Ser. Khim., 2001, 1000 [Russ. Chem. Bull., Int. Ed., 2001, 50, 1044].
W. Rudorf, Tetrahedron, 1984, 2, 381.
V. Ya. Popkova, M. V. Galakhov, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 1989, 116 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989, 38, 114 (Engl. Transl.)].
V. I. Krokhtyak, A. Ya. Il´chenko, and L. M. Yagupol´skii, Zh. Org. Khim., 1981, 17, 268 [J. Org. Chem. USSR, 1981, 17 (Engl. Transl.)].
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kovregin, A.N., Sizov, A.Y. & Ermolov, A.F. Chlorolysis of β-functionalized alkyl polyfluoroalkenyl sulfides. Russian Chemical Bulletin 51, 1031–1034 (2002). https://doi.org/10.1023/A:1019673921176
Issue Date:
DOI: https://doi.org/10.1023/A:1019673921176