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ESR spectra of products of oxidation of endometallofullerenes M@C82 (M = Y, La, Ce, Gd)

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Abstract

The ESR spectra of the products of oxidation of solutions and powders of Y@C82 and La@C82 with fuming sulfuric acid were studied. Based on the oxidation conditions and the sequence of spectral patterns, the spectra were attributed to the radical cations M@C82 n+ (n = 2, 4), dimers M3+ 2@C164 +, and polyendometallofullerenes.

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Authors and Affiliations

  1. Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. P. Solodovnikov, B. L. Tumanskii, V. V. Bashilov & V. I. Sokolov

  2. Forschungszentrum Karlsruhe, Institut für Nukleare Festkörperphysik, D-76021, Karlsruhe, Germany

    S. F. Lebedkin

Authors
  1. S. P. Solodovnikov
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  2. B. L. Tumanskii
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  3. V. V. Bashilov
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  4. S. F. Lebedkin
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  5. V. I. Sokolov
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Solodovnikov, S.P., Tumanskii, B.L., Bashilov, V.V. et al. ESR spectra of products of oxidation of endometallofullerenes M@C82 (M = Y, La, Ce, Gd). Russian Chemical Bulletin 51, 1009–1014 (2002). https://doi.org/10.1023/A:1019665719359

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  • DOI: https://doi.org/10.1023/A:1019665719359

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