Abstract
The effect of UV or visible light on solutions of 1-benzoyloxy-4-[4-(dimethylamino)styryl]pyridinium salts in acetonitrile solution lead to cleavage of the N—O bond and formation of 4-[4-(dimethylamino)styryl]pyridine.
Similar content being viewed by others
REFERENCES
J. V. Crivello and S. Y. Song, Chem. Mater., 12, No.12, 3674-3680 (2001).
J. V. Crivello, J. Polym. Chem., 37, No.23, 4241-4254 (1999).
J. V. Crivello and N. Y. Elnora, “Photopolymerizable composition containing group Y and aromatic onium salts,” USA Pat. 4069056, IPC 96/115 P (G03 C 1/68, C 08 F 8/18), General Electric Co. No.638393, Publ. June 17, 1978.
O. Shimomura, I. Tomita, and T. Endo, J. Polym. Chem., 39, No.6, 868-871 (2001).
E. Irving and P. Stark, Brit. Polym. J., 15, No.3, 24-29 (1983).
A. R. Katritzky, Z. Deqa-Szafran, C. H. Watson, and D. R. Eyler, J. Chem. Soc., Perkin Trans. II, No.6, 1051-1057 (1990).
A. R. Katritzky, R. D. Burton, P. A. Shipkova, et al., J. Chem. Soc., Perkin Trans. II, No.2, 835-840 (1998).
G. D. Titskii, and M. K. Turovskaya, Zh. Org. Khim., 28, No.9, 1911-1917 (1992).
G. D. Titskii and T. S. Gaidash, Teor. Éksp. Khim., 34, No.5, 286-289 (1998).
W. Jencks and M. Gilchrist, J. Am. Chem. Soc., 90, No.10, 2622-2637 (1968).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Titskii, G.D., Turovskaya, M.K. Photochemical Cleavage of the N—O Bond in 1-Benzoyloxy-4-[4-(dimethylamino)styryl]pyridinium Salts. Theoretical and Experimental Chemistry 38, 192–194 (2002). https://doi.org/10.1023/A:1019661120327
Issue Date:
DOI: https://doi.org/10.1023/A:1019661120327