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Crystal Structure of the Mixed-Ligand Compound [HgPhen{(C2H5)2NCS2}2] and the Character of Intermolecular Interactions in [MPhen{(C2H5)2NCS2}2] (M = Zn, Cd, Hg)

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Abstract

Single crystals of the mixed-ligand complex compound [HgPhen(Et2NCS2)2] were obtained. The crystal structure of the compound was determined by X-ray diffraction analysis (CAD-4 diffractometer, Mo\(K_\alpha \) radiation, 3640 F hkl , R = 0.0280). Triclinic crystals with cell parameters a = 10.308(2), b = 11.171(3), c = 11.552(2) Å, α = 94.16(2), β = 96.66(1), γ = 105.17(2)°, V = 1267.8(5) Å3, Z = 2, d calc = 1.774 g/cm3, space group \(P\bar 1\). The structure is composed of discrete monomer molecules. The coordination polyhedron of the Hg atom is a distorted octahedron formed by four S atoms of the two cyclic bidentate Et2 \(NCS_{2^ - } \) ligands and two N atoms of the cyclic bidentate Phen ligand. The character of interactions between [MPhen(Et2NCS2)2] (M = Zn, Cd, Hg) molecules and their packing in the structure are considered.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Russia

    R. F. Klevtsova, L. A. Glinskaya, S. M. Zemskova & S. V. Larionov

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  1. R. F. Klevtsova
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  2. L. A. Glinskaya
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  3. S. M. Zemskova
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  4. S. V. Larionov
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Klevtsova, R.F., Glinskaya, L.A., Zemskova, S.M. et al. Crystal Structure of the Mixed-Ligand Compound [HgPhen{(C2H5)2NCS2}2] and the Character of Intermolecular Interactions in [MPhen{(C2H5)2NCS2}2] (M = Zn, Cd, Hg). Journal of Structural Chemistry 43, 322–329 (2002). https://doi.org/10.1023/A:1019660810253

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