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The First-Stage Kinetics of the Iron Anodic Ionization in Acidic Sulfate Solutions

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Abstract

The hypothesis that water molecules are involved in the anodic dissolution of iron in acidic sulfate solutions is confirmed experimentally. The oxidation of Fe0 iron to Fe+ is shown to proceed in stages: at the first stage, the interaction between the metal and water molecules results in the formation of surface charge-transfer complexes, which then decompose to form the adsorbed OH groups. The charge transfer in the complexes is estimated to be about 0.5.

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REFERENCES

  1. Bockris, J.O'M., Drazic, D., and Despic, A., Electrochim. Acta, 1961, vol. 4, nos. 2-4, p. 325.

    Google Scholar 

  2. Bockris, J.O'M., and Kita, H., J. Electrochem. Soc., 1961, vol. 108, no. 7, p. 676.

    Google Scholar 

  3. Bockris, J.O'M., and Drazic, D., Electrochim. Acta, 1962, vol. 7, nos. 5-6, p. 293.

    Google Scholar 

  4. Bonhoeffer, K.F. and Heusler, K.E., Z. Phys. Chem. (Munich), 1956, vol. 8, no. 3, p. 390.

    Google Scholar 

  5. Bonhoeffer, K.F. and Heusler, K.E., Z. Elektrochem., 1957, vol. 61, no. 1, p. 122.

    Google Scholar 

  6. Bonhoeffer, K.F. and Heusler, K.E., Z. Elektrochem., 1958, vol. 62, no. 5, p. 582.

    Google Scholar 

  7. Kolotyrkin, Ya.M., Lazorenko-Manevich, R.M., and Sokolova, L.A., J. Electroanal. Chem., 1987, vol. 228, nos. 1-2, p. 301.

    Google Scholar 

  8. Florianovich, G.M. and Lazorenko-Manevich, R.M., Itogi Nauki Tekh., Ser.: Korr. Zashch. Korr., 1990, vol. 16, p. 3.

    Google Scholar 

  9. Lazorenko-Manevich, R.M. and Sokolova, L.A., Elektrokhim., 1998, vol. 34, no. 9, p. 933.

    Google Scholar 

  10. Lazorenko-Manevich, R.M., Podobaev, A.N., and Sokolova, L.A., Ros. Khim. Zhurn. (Zhurn. Vsesoyuznogo Khimicheskogo Obshchestva im. D.I. Mendeleeva), 1998, vol. 42, no. 4, p. 75.

    Google Scholar 

  11. Lazorenko-Manevich, R.M. and Sokolova, L.A., Elektrokhim., 1998, vol. 34, no. 6, p. 939.

    Google Scholar 

  12. Lazorenko-Manevich, R.M. and Sokolova, L.A., Elektrokhim., 1999, vol. 35, no. 12, p. 1424.

    Google Scholar 

  13. Lazorenko-Manevich, R.M. and Podobaev, A.N., Zashch. Met., 2001, vol. 37, no. 5, p. 1.

    Google Scholar 

  14. Lazorenko-Manevich, R.M., Sokolova, L.A., and Kolotyrkin, Ya.M., Elektrokhim., 1978, vol. 14, no. 12, p. 1779.

    Google Scholar 

  15. Podobaev, A.N., Reformatskaya, I.I., and Krivokhvostova, O.V., Zashch. Met., 2000, vol. 36, no. 4, p. 352.

    Google Scholar 

  16. Podobaev, A.N., Lazorenko-Manevich, R.M., and Danibakhchieva, L.E., Elektrokhim., 1997, vol. 33, no. 9, p. 1098.

    Google Scholar 

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  1. Karpov Institute of Physical Chemistry, ul. Vorontsovo Pole 10, Moscow, 103064, Russia

    A. N. Podobaev & O. V. Krivokhvostova

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  1. A. N. Podobaev
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  2. O. V. Krivokhvostova
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Podobaev, A.N., Krivokhvostova, O.V. The First-Stage Kinetics of the Iron Anodic Ionization in Acidic Sulfate Solutions. Protection of Metals 38, 329–332 (2002). https://doi.org/10.1023/A:1019653132621

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