Abstract
The mercury derivatives of primary nitramines were proved by molecular spectroscopy and quantum-chemical calculations to be covalent compounds. The mercury atom was found to be coordinated to the amine nitrogen atom.
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V. I. Slovetskii, V. A. Tartakovskii, and S. S. Novikov, Izv. Akad. Nauk, Otd. Khim. Nauk [Bull. Acad. Sci. USSR, Div. Chem. Sci.], 1962, 1400 (in Russian).
M. J. Brookes and N. J. Jonathan, J. Chem. Soc., A, 1968, 2266.
V. A. Shlyapochnikov, Kolebatel´nye spektry alifaticheskikh nitrosoedinenii [Vibrational Spectra of Aliphatic Nitro Compounds], Nauka, Moscow, 1989, 136 pp. (in Russian).
V. A. Shlyapochnikov, N. O. Cherskaya, V. P. Ivshin, T. N. Ivshina, and K. I. Bakhtin, Zh. Org. Khim., 1983, 53, 2334 [J. Org. Chem. USSR, 1983, 53 (Engl. Transl.)].
N. O. Cherskaya, V. A. Shlyapochnikov, V. P. Ivshin, and T. N. Ivshina, Izv. Akad. Nauk SSSR, Ser. Khim., 1986, 1533 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986, 35, 1388 (Engl. Transl.)].
S. S. Novikov, G. F. Shvekhgeimer, V. V. Sevost´yanova, and V. A. Shlyapochnikov, in Khimiya alifaticheskikh i atsiklicheskikh nitrosoedinenii [Chemistry of Aliphatic and Acyclic Nitro Compounds], Khimiya, Moscow, 1974, 350 (in Russian).
V. G. Avakyan, V. A. Shlyapochnikov, O. A. Luk´yanov, and V. A. Tartakovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1972, 590 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1972, 21, 548 (Engl. Transl.)].
M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, V. G. Zakrzewski, J. A. Montgomery, Jr., R. E. Stratmann, J. C. Burant, S. Dapprich, J. M. Millam, A. D. Daniels, K. N. Kudin, M. C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi, B. Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G. A. Petersson, P. Y. Ayala, Q. Cui, K. Morokuma, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. Cioslowski, J. V. Ortiz, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, C. Gonzalez, M. Challacombe, P. M. W. Gill, B. Johnson, W. Chen, M. W. Wong, J. L. Andres, C. Gonzalez, M. Head-Gordon, E. S. Replogle, and J. A. Pople, GAUSSIAN-98, Rev. A.3, Gaussian, Inc., Pittsburgh (PA), 1998.
H. Ley and E. Kissel, Ber., 1899, 32, 1864.
H. Backer, Samml. Chem. Chem.-Techn. Vortrage, 1912, 18, No. 10/12, 350.
S. F. Palopoli, S. J. Geib, A. L. Rheingold, and T. B. Brill, Inorg. Chem., 1988, 27, 2963.
V. G. Avakyan, V. A. Chekrygin, V. A. Shlyapochnikov, and A. I. Kislinskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1969, 2606 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1969, 18 (Engl. Transl.)].
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Shlyapochnikov, V.A., Cherskaya, N.O., Ivshin, V.P. et al. Spectra and structure of mercury derivatives of primary nitramines. Russian Chemical Bulletin 51, 1071–1074 (2002). https://doi.org/10.1023/A:1019642508881
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DOI: https://doi.org/10.1023/A:1019642508881