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Acylotropic Tautomerism: XXXV. RL-Inversion of Configuration of Dipolar Spyrocyclic and Open-Chain 2-Arylaminotropone Isomers

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Abstract

RL-Inversion of chiral spirocyclic and open-chain 2-arylaminotropone derivatives with varied heteroatom (O, S, N) has been studied. Kinetic relations holding in the RL-permutation are discussed. Its mechanism includes formation and dissociation of spiro bonds and torsion stereodynamics.

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Authors and Affiliations

  1. Rostov State University, ul. Zorge 7, Rostov-on-Don, 344090, Russia

    L. P. Olekhnovich, S. V. Kurbatov, G. S. Vaslyaeva & Yu. A. Zhdanov

  2. Research Institute of Physical and Organic Chemistry, Rostov State University, pr. Stachki 194/3, Rostov-on-Don, 344104, Russia

    Z. N. Budarina & G. S. Borodkin

Authors
  1. L. P. Olekhnovich
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  2. Z. N. Budarina
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  3. G. S. Borodkin
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  4. S. V. Kurbatov
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  5. G. S. Vaslyaeva
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  6. Yu. A. Zhdanov
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Olekhnovich, L.P., Budarina, Z.N., Borodkin, G.S. et al. Acylotropic Tautomerism: XXXV. RL-Inversion of Configuration of Dipolar Spyrocyclic and Open-Chain 2-Arylaminotropone Isomers. Russian Journal of Organic Chemistry 38, 713–722 (2002). https://doi.org/10.1023/A:1019619307779

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  • DOI: https://doi.org/10.1023/A:1019619307779

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