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Potentially hexadentate bisazine dioximate ligands: “correct” synthetic procedure and encapsulation reactions of the iron(ii) ion

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Abstract

Condensation of diacetyl monoxime hydrazone with diacetyl, hexane-3,4-dione, and glyoxal in MeOH afforded potentially hexadentate bisazine dioximes. The crystal and molecular structure of the condensation product with diacetyl was established by X-ray diffraction analysis. The reactions of the resulting azine oximes with Fe2+ ions in the presence of Lewis acids were studied.

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References

  1. J.-M. Lehn, Supramolecular Chemistry, VCH, Weinheim, 1995.

    Google Scholar 

  2. N. A. Kostromina, Ya. Z. Voloshin, and A. Yu. Nazarenko, Klatrokhelaty: sintez, stroenie, svoistva [Clathrochelates: Syn-thesis, Structure, Properties], Naukova Dumka, Kiev, 1992, 234 pp. (in Russian).

    Google Scholar 

  3. Ya. Z. Voloshin, Ross. Khim. Zh., 1998, 42, 5 [Mendeleev Chem. J., 1998, 42 (Engl. Transl.)].

    Google Scholar 

  4. Ya. Z. Voloshin, O. A. Varzatskii, T. E. Kron, V. K. Belsky, V. E. Zavodnik, N. G. Strizhakova, and A. V. Palchik, Inorg. Chem., 2000, 39, 1907.

    Google Scholar 

  5. Y. Z. Voloshin, O. A. Varzatskii, E. Y. Tkachenko, Y. A. Maletin, S. P. Degtyarev, and D. I. Kochubey, Inorg. Chim. Acta, 1997, 255, 255.

    Google Scholar 

  6. R. Dey, J. Chem. Soc., 1914, 105, 1042; H. Daparsky and E. Spannagel, J. Pract. Chem., 1910, 92, 283; Beilsteins Handbuch der Organischen Chemie, I. Ergänzungswerk, Springer, Berlin, 1928, 396; 399.

    Google Scholar 

  7. H. C. Barany, E. A. Braude, and M. Planka, J. Chem. Soc., 1951, 1929.

  8. M. O. Forster and B. B. Dey, J. Chem. Soc., 1912, 101, 2234.

    Google Scholar 

  9. SMART and SAINT, Release 5.0, Area Detector Control and Integration Software, Bruker AXS, Analitical X-Ray Instruments, Madison, Wisconsin, USA, 1998.

  10. G. M. Sheldrick, SADABS: A Program for Exploiting the Redundancy of Area-Detector X-ray Data, University of Göttingen, Germany, 1999.

    Google Scholar 

  11. G. M. Sheldrick, SHELXTL PC Version 5.0. An Integrated System for Solving, Refining, and Displaying Crystal Structures from Diffraction Data, Siemens Analytical X-Ray Instruments, Inc., Madison, WI, 1994.

    Google Scholar 

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Authors and Affiliations

  1. State Research Center of the Russian Federation “L. Ya. Karpov Institute of Physical Chemistry”, 10 ul. Vorontsovo Pole, 105064, Moscow, Russian Federation

    Ya. Z. Voloshin

  2. V. I. Vernadskii Institute of General and Inorganic Chemistry, 32/34 ul. Palladina, 252142, Kiev, Ukraine

    O. A. Varzatskii & E. Yu. Tkachenko

  3. Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds, 28 ul. Vavilova, 199991, Moscow, Russian Federation

    I. I. Vorontsov & M. Yu. Antipin

Authors
  1. Ya. Z. Voloshin
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  2. O. A. Varzatskii
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  3. I. I. Vorontsov
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  4. M. Yu. Antipin
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  5. E. Yu. Tkachenko
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Voloshin, Y.Z., Varzatskii, O.A., Vorontsov, I.I. et al. Potentially hexadentate bisazine dioximate ligands: “correct” synthetic procedure and encapsulation reactions of the iron(ii) ion. Russian Chemical Bulletin 51, 1015–1019 (2002). https://doi.org/10.1023/A:1019617803429

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  • DOI: https://doi.org/10.1023/A:1019617803429

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