Abstract
Diazotization of 4-amino-2,2,6,6-tetramethylpiperidine in acetic or sulfuric acid affords 2,2,6,6- tetramethyl-1,2,3,6-tetrahydropyridine in high yield. Under the same conditions, the corresponding nitroxyl radical transforms into 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl.
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REFERENCES
Dagonneau, M., Ivanov, V.B., Rozantsev, E.G., et al., J. Macromol. Sci., 1982-1983, no. 2, pp. 169-202.
Rozantsev, E.G., Sholle, V.D., Ivanov, V.B., et al., in Polymer Stabilization and Degradation, Washington DC: Am. Chem. Soc., 1985, pp. 11-37.
Rozantsev, E.G., Svobodnye iminoksil'nye radikaly (Free Iminoxyl Radicals), Moscow: Khimiya, 1970.
Avrutskaya, I.A., Kagan, E.Sh., Smirnov, V.A., and Fioshin, M.Ya., Nitroksil'nye radikaly: sintez, khimiya i prilozheniya (Nitroxyl radicals: Synthesis, Chemistry, and Applications), Moscow: Nauka, 1987.
Dagonneau, M., Sholle, V.D., Rozantsev, E.G., et al., Synthesis, 1984, no. 11, pp. 895-916.
Rozantsev, E.G., Golubev, V.A., and Neiman, M.B., Izv. Akad. Nauk SSSR, Ser. Khim., 1965, no. 2, pp. 391-393.
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Kashparova, V.P., Kagan, E.S., Kashparov, I.S. et al. Synthesis of 2,2,6,6-Tetramethylpiperidine Derivatives. Russian Journal of Applied Chemistry 75, 667–668 (2002). https://doi.org/10.1023/A:1019597921100
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DOI: https://doi.org/10.1023/A:1019597921100