Abstract
The acid-catalyzed liquid-phase dehydration of dimethylphenylmethanol to α-methylstyrene was considered. The scheme and mathematical model of liquid-phase dehydration of dimethylphenylmethanol were proposed, and the effect of acetophenone on the reaction kinetic parameters was studied.
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REFERENCES
Kruzhalov, B.D. and Golovanenko, B.I., Sovmestnoe proizvodstvo fenola i atsetona (Combined Production of Phenol and Acetone), Moscow: Goskhimizdat, 1963.
CSSR Patent 248 562B1.
JPN Patent 61 293 936A2.
Polyanskii, N.G. and Polyanskaya, N.L., Tr. Tambovsk. Inst. Khim. Mashinostr., 1969, no. 3, pp. 84-91.
GDR Patent 161 239.
Zuolin, Z. and James, H.E., J. Org. Chem., 1996, vol. 61, no. 1, pp. 324-328.
US Patent 5 245 090.
Safronov, V.S., Bogomolova, G.Ya., Smirnov, B.Yu., et al., Khim. Prom-st., 1991, vol. 31, no. 8, pp. 461-468.
McNair, H.M. and Bonelli, E.J., Basic Gas Chromatography, Walnut Creek, CA: Varian Aerograph, 1967.
Fiezer, L.F. and Fiezer, M., Advanced Organic Chemistry, New York: Reinhold, 1962; Fiezer, L.F. and Fiezer, M., Current Topic in Organic Chemistry, New York: Reinhold, 1964.
Lebedev, N.N., Manakov, M.N., and Shvets, V.F., Teoriya khimicheskikh protsessov osnovnogo organicheskogo i neftekhimicheskogo sinteza (Theory of Chemical Processes of Basic Organic and Petrochemical Synthesis), Moscow: Khimiya, 1984.
Shmidt, R. and Sapunov, V.N., Non-Formal Kinetics, Weinheim: Chemie, 1982.
Reichardt, Ch., Solvents and Solvent Effects in Organic Chemistry, Weinheim: VCH, 1988.
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Mamedov, E.M., Gagarin, M.A. & Kharlampidi, K.E. Effect of Acetophenone on Liquid-Phase Dehydration of Dimethylphenylmethanol. Russian Journal of Applied Chemistry 75, 585–588 (2002). https://doi.org/10.1023/A:1019517130669
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DOI: https://doi.org/10.1023/A:1019517130669