Abstract
The optical properties of ruthenium silicide Ru2Si3 have been studied theoretically and experimentally. The energy band spectrum and optical properties were simulated with the aid of the first‐principle self‐consistent method of linear attached plane waves. The spectral dependence of the absorption coefficient in the 0.52.2 eV energy range was measured experimentally by the photothermal refractive spectroscopy method. It is established that ruthenium silicide is a direct‐gap semiconductor having an energy gap of 0.84 eV and a low oscillator strength of the first direct transition.
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REFERENCES
L. Ivanenko, H. Lange, A. Heinrich, in: V. E. Borisenko (ed.), Semiconducting Silicides, Springer, Berlin (2000), pp. 243–297.
D. J. Poutcharovsky and E. Parthé, Acta Cryst. B, 30, 2692–2696 (1974).
D. J. Poutcharovsky, K. Yvon, and E. Parthé, J. Less-Common Met., 40, No. 1, 139–144 (1975).
P. Blaha, K. Schwarz, P. Sorantin, and S. B. Trickey, Comput. Phys. Commun., 59, 399–402 (1990).
J. P. Perdew, J. A. Chevary, S. H. Vosko, K. A. Jackson, M. R. Pederson, D. J. Singh, and C. Fiolhais, Phys. Rev. B, 46, No. 11, 6671–6687 (1992).
W. Wolf, G. Bihlmayer, and S. Bluegel, Phys. Rev. B, 55, No. 11, 6918–6926 (1997).
W. Henrion, M. Rebien, V. N. Antonov, O. Jepsen, and H. Lange, Thin Solid Films, 313/314, 218–221 (1998).
A. B. Filonov, D. B. Migas, V. L. Shaposhnikov, N. N. Dorozhkin, V. E. Borisenko, A. Heinrich, and H. Lange, Phys. Rev. B, 60, No. 24, 16494–16498 (1999).
W. Henrion, M. Rebien, A. G. Birdwell, V. N. Antonov, and O. Jepsen, Thin Solid Films, 364, 171–176 (2000).
J. S. Sharpe, Y. L. Chen, R. M. Gwilliam, A. K. Kewell, C. N. McKinty, M. A. Lourenc,o, G. Shao, K. P. Homewood, and K. Reeson Kirkby, Appl. Phys. Lett., 75, No. 9, 1282–1283 (1999).
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Ivanenko, L.I., Shaposhnikov, V.L., Borisenko, V.E. et al. Optical Properties of Semiconducting Ruthenium Silicide. Journal of Applied Spectroscopy 68, 320–325 (2001). https://doi.org/10.1023/A:1019284623475
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DOI: https://doi.org/10.1023/A:1019284623475