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Interactions in the Nitrobenzene–Molecular Sieves System

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Abstract

Implantation of nitrobenzene into the inner space of aluminosilicate mesoporous molecular sieves of the MSM–41 type was investigated. The interaction of nitrobenzene with the active centers of the inner surface of channels was studied by the method of IR spectroscopy. It was hypothesized that the possible mechanism of this interaction is the formation of hydrogen bonds of the –NO2...HO–Al(Si) type.

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Authors and Affiliations

  1. Institute of Physics, National Academy of Sciences of Ukraine, 46 Nauka Ave., Kiev, 03028, Ukraine

    T. V. Bezrodnaya & G. A. Puchkovskaya

  2. Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Kiev

    Yu. G. Gol'tsov & L. A. Matkovskaya

  3. Institute of Low Temperatures and Structural Investigations, Polish Academy of Sciences, Wroclaw, Poland

    Ya. Baran

Authors
  1. T. V. Bezrodnaya
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  2. G. A. Puchkovskaya
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  3. Yu. G. Gol'tsov
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  4. L. A. Matkovskaya
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  5. Ya. Baran
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Bezrodnaya, T.V., Puchkovskaya, G.A., Gol'tsov, Y.G. et al. Interactions in the Nitrobenzene–Molecular Sieves System. Journal of Applied Spectroscopy 68, 26–31 (2001). https://doi.org/10.1023/A:1019248700197

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  • DOI: https://doi.org/10.1023/A:1019248700197

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