Abstract
We show that the modified partitioning procedure can be applied to study the spherical and nonspherical Stark effect in the hydrogen atom and the spherical quadratic Zeeman effect in H-, the helium atom and He‐like ions: Li++, Be++, etc. We present ground‐state energy values for γ (in a.u.) in the interval 0.001 ≤ λ ≤ 0.2 (a.u.= 5.142·109 volts/cm) and for magnetic field γ (in a.u.) in the interval 0.1 ≤ γ ≤ 1.0 (a.u. = 2.353·109 gauss). We compare our results to values available in the literature; they are, in general, better than those obtained by other methods.
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S.P. Alliluev and V.S. Popov, Zh. Eksp. Teor. Fiz. 104 (1993) 3569.
J. Austin, Mol. Phys. 42 (1981) 1391.
L. Benassi and V. Grecchi, J. Phys. B: At. Mol. Phys. 13 (1980) 911.
H.S. Brandi, Phys. Rev. A 11 (1976) 1835.
B. Cabib, E. Fabri and G. Fiorio, Nuovo Cimento B 10 (1972) 185.
D. Farrelly and W.P. Reinhardt, J. Phys. B: At. Mol. Phys. 16 (1983) 2103.
G. Fonte, P. Falsaperla, G. Schiffrer and D. Stanzial, Phys. Rev. A 41 (1990) 5807.
R.H. Garstang, Rep. Prog. Phys. 40 (1997) 105.
A.V. Gluskov and L.N. Ivanov, J. Phys. B: At. Mol. Opt. Phys. 26 (1993) 1379.
J. Gómes and J. Sesma, Phys. Lett. A 219 (1996) 187.
F.Y. Hajj, J. Phys. B: At. Mol. Opt. Phys. 26 (1993) 613.
J.W.R. Henry, R.F. O'Connell, R. Smith, G. Chanmugam and A.K. Rajagopal, Phys. Rev. D 9 (1974) 329 and references therein.
M. Hehenberger, H.V. McItosh and E. Brändas, Phys. Rev. A 10 (1974) 1494.
S.C. Kanavi and S.H. Patil, Phys. Rev. A 24 (1981) 331.
J. Killingbeck, J. Phys. A 10 (1977) 199.
J. Killingbeck, Phys. Lett. A 65 (1978) 87.
J. Killingbeck, J. Phys. B: At. Mol. Phys. 12 (1979) 25.
J. Killingbeck and S. Galicia, J. Phys. A 13 (1980) 3419.
J.C. Le Guillou and J. Zinn-Justin, Ann. Phys. 147 (1983) 57.
P.G. Logrado and J.D.M. Vianna, J. Math. Chem. 22 (1997) 107.
P.O. Löwdin, J. Math. Phys. 3 (1962) 969; Phys. Rev. A 139 (1965) 357.
R.O. Mueller, A.R.P. Rau and L. Spruch, Phys. Rev. A 11 (1975) 789 and references therein.
V.S. Popov, V.D. Mur, A.V. Sergeev and V.M. Weinberg, Phys. Lett. A 149 (1990) 418.
H.C. Praddaude, Phys. Rev. A 6 (1972) 132.
W. Rösner, G. Wummer, H. Herold and H. Ruder, Phys. Rev. B 17 (1984) 29.
R. Silva and S. Canuto, Phys. Lett. A 88 (1982) 282.
J.R. Silva and S. Canuto, Phys. Lett. A 101 (1984) 326.
J. Silvestone, Phys. Rev. A 18 (1978) 1853.
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Logrado, P., Vianna, J. Partitioning technique procedure revisited II: Application to the Stark and Zeeman problems in light atoms. Journal of Mathematical Chemistry 26, 1–13 (1999). https://doi.org/10.1023/A:1019165307456
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DOI: https://doi.org/10.1023/A:1019165307456